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Steady-state kinetics and osillation phenomena for complete oxidation of benzene over Pt/Al_2O_3 catalyst

Steady-state kinetics and osillation phenomena for complete oxidation of benzene over Pt/Al_2O_3 catalyst
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摘要 The steady-state kinetics for complete oxidation of benzene over has been investigated by the external recycling reactor. The kinetics equation was described by the L-H model of adsorption of benzene and oxygen with the inhibition of carbon dioxide. The parameters of the kinetics model were estimated by the method of orthogonal design. The heats of adsorption of benzene, oxygen and carbon dioxide were determined by the method of gas-adsorption chromatography. The details of oscillations of complete oxidation of benzene were investigated. The steady-state kinetics for complete oxidation of benzene over has been investigated by the external recycling reactor. The kinetics equation was described by the L-H model of adsorption of benzene and oxygen with the inhibition of carbon dioxide. The parameters of the kinetics model were estimated by the method of orthogonal design. The heats of adsorption of benzene, oxygen and carbon dioxide were determined by the method of gas-adsorption chromatography. The details of oscillations of complete oxidation of benzene were investigated.
出处 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 1990年第2期41-50,共10页 环境科学学报(英文版)
基金 Supported by the National Sciences Fundation of China.
关键词 steady-state kinetics complete oxidation BENZENE Pt/Al2O3. steady-state kinetics complete oxidation benzene Pt/Al2O3.
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