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HYPERSENSITIVITY IN THE ABSORPTION SPECTRA OF Nd^(3+) and Er^(3+) COMPLEXES WITH AMINO ACIDS

HYPERSENSITIVITY IN THE ABSORPTION SPECTRA OF Nd^(3+) and Er^(3+) COMPLEXES WITH AMINO ACIDS
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摘要 Spectroscopic properties of Nd^(3+),Er^(3+)-glutamic acid,aspartic acid and asparagine systems are investi- gated at different pH values and different Ln^(3+):amino acid ratios.The existence of 1:1 and 1:2.75 species in solution of pH=1~5 is proved.The dependence of oscillator strength of “hypersensitive” transition and parameter T_2 on acidic-basic properties of the ligand and correlation between oscillator strength of “hypersensitive” transition and parameter T_2 are discussed. Spectroscopic properties of Nd^(3+),Er^(3+)-glutamic acid,aspartic acid and asparagine systems are investi- gated at different pH values and different Ln^(3+):amino acid ratios.The existence of 1:1 and 1:2.75 species in solution of pH=1~5 is proved.The dependence of oscillator strength of “hypersensitive” transition and parameter T_2 on acidic-basic properties of the ligand and correlation between oscillator strength of “hypersensitive” transition and parameter T_2 are discussed.
出处 《Journal of Rare Earths》 SCIE EI CAS CSCD 1990年第2期87-91,共5页 稀土学报(英文版)
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