SYNTHESIS AND MAGNETISM OF BINUCLEAR COPPER(Ⅱ) COMPLEXES CONTAINING SALUCYLAMIDATOCUPRATE(Ⅱ)

<正> New binuclear copper（Ⅱ） complexes, [Cu（samen）Cu（NO2-phen）]·H2O and [Cu（sampn）-Cu（NO2-phen）]·2H2O have been synthesized, where samen4-, sampn4-and NO2-phen denote N, N′-ethylenedisalicylamidate anion, N, N′-1, 2-propanedisalicylamidate anion and 5-nitro-1, 10-phenanthroline respectively. 3ased on IR, elemental analyses and electronic spectra, the complexes are proposed to have a phenoxy-bridged structure and to consist of the Cu（Ⅱ）ion in distorted planar environment. The complexes have been characterized with varlable-temperature magnetic susceptibility （4—300 K） and the observed data were fit to those from a modified Bleaney-Bowers equation by least-squares method, giving the exchange integral J=-63.0 cm-1（samen） and J=-46.5cm-1（sampn）. This indicates the existence of antiferromagnetic spin exchange interaction among the metal ions.

New binuclear copper（Ⅱ） complexes, [Cu（samen）Cu（NO2-phen）]·H2O and [Cu（sampn）-Cu（NO2-phen）]·2H2O have been synthesized, where samen4-, sampn4- and NO2-phen denote N, N′-ethylenedisalicylamidate anion, N, N′-1, 2-propanedisalicylamidate anion and 5-nitro-1, 10-phenanthroline respectively. 3ased on IR, elemental analyses and electronic spectra, the complexes are proposed to have a phenoxy-bridged structure and to consist of the Cu（Ⅱ）ion in distorted planar environment. The complexes have been characterized with varlable-temperature magnetic susceptibility （4—300 K） and the observed data were fit to those from a modified Bleaney-Bowers equation by least-squares method, giving the exchange integral J=-63.0 cm-1 （samen） and J=-46.5cm-1 （sampn）. This indicates the existence of antiferromagnetic spin exchange interaction among the metal ions.