硬软酸碱原理在有机硫化物反应中的应用

THE APPLICATIONS OF HARD SOFTACIDS BASES PRINCIPLE TO THEREACTIONS OF ORGANOSULFURCOMPOUNDS

运用硬软酸碱原理讨论有机硫化物各种类型的反应实例,并将锍叶立德重排,二甲亚砜的R.Pummerer反应,N.Kornblum反应,重金属中毒及解毒机理用硬软酸碱原理进行解释。

In this article, all kinds of reactions of Organosulfur Compounds is discussed with the help of the Hard Soft Acids Bases (HSAB) principle. It is an attempt to apply the HSAB principle to explainate the rearrange ment reactions of Sulphur R.Pummerer N. Kornblum reactions of Dimethyl Sulphoxid, the mechanism of the poisoning and detoxicating of heavy metals.