摘要
本文总结了Diels—Alder反应在硅橡胶加工和聚硅烷合成方面的应用,其中包括:(一) 利用该反应合成了含多苯苯基或稠环的硅橡胶交联剂和耐热助剂;(二) 通过该反应建立了硅橡胶新型硫化体系,不外加催化剂;(三) 通过该反应合成了含多苯苯基或稠环的有机硅单体,进而制出许多新型聚硅烷;(四) 探讨了影响硅橡胶各种性能的因素及大芳基对聚硅烷性能的影响。
A review on advances in developing the application of Diels-Alder reaction in the organosilicon polymer chemistry in our laboratory is presented. Using the reaction mentioned above, we have synthesized a series of organo-silicon monomers and polymer with polyphenyl phenyl groups and condensed rings, established novel vulcauization system for silicone rubber. In addition, We have discussed the influences of the large aromatic groups on the properties of the polymers.
出处
《化学研究与应用》
CAS
CSCD
1990年第1期2-17,共16页
Chemical Research and Application
