[M(H_2O)_3(NCS)_3](18-冠-6)[M=Cr(Ⅲ)或Fe(Ⅲ)]配合物的合成和物性表征

THE STUDIES ON SYNTHESES AND CHARACTERIZATIONS OF [M(H_2O)_3(NCS)_3] (18—CROWN—6) [M=Cr(Ⅲ) Fe(Ⅲ)]

我们曾对二价的过渡金属与18—冠—6配合物的合成与表征进行研究。本文用凝胶法得到标题的两种三价过渡金属离子的组成类似韵配合物晶体,并对它们进行了组成分析和多项物理性质的测试和表征。而其中的铬配合物作者已进行X射线单晶结构分析。

The two title complex crystals have been synthesized by gel method. The complexes were charaterized by elemental and thermal analyses, visible spectrum, IR, MS etc. Thereby the structures of two analogical complexes have been infered.