摘要
在酸性条件下,丙酮缩合成异丙基丙酮,再与乙二胺反应生成β-氨基酮,再与另一酮基缩合得到[(14)4,11-二烯-N4]2HI,最后分别与Ni(OAc)2.4H2O和Co(OAc)2.4H2O进行反应,得到大环配合物[Ni((14)4,11-二烯-N4)]I2和[Co((14)4,11-二烯-N4)]I2,其结构经IR、1 HNMR、13 CNMR验证。
In acidic conditions,acetone condensed to form isopropyl acetone then reacted with ethylenediamine to form β-amino ketone then condensed with another ketone to form[（14）4,11-diene-N4]2HI,and then respectively reacted with Ni（OAc）2·4H2O and Co（OAc）2·4H2O to form macrocyclic complexs[Ni（（14） 4,11-diene-N4）]I2 and [Co（（14） 4,11-diene-N4）]I2.Their structures were confirmed by IR,1HNMR,13CNMR.
出处
《化学与生物工程》
CAS
2011年第11期51-53,共3页
Chemistry & Bioengineering
关键词
钴
镍
大环配合物
大环配体
cobalt
nickel
macrocyclic complex
macrocyclic ligand
