摘要
we developed a new silicate-based full-color phosphor Ba3Lu2(SiO4)3:Eu2+ through solid state reaction.The host crystal structure was isostructural with Ca3Y2(SiO4)3 instead of garnet-type.The phosphor absorbed near-ultraviolet light from 250 to 400 nm,which was very suitable for a color converter of white LED that used UV-LED as the primary light source.The photoluminescence peak wavelength of Ba3Lu2(SiO4)3:Eu2+ was about 461 nm and a shoulder peak was around 522 nm,which resulted from the 5d-4f transition of the Eu2+.The optimum concentration of Eu2+ was 3.45 mol.% of Ba2+ content in Ba3Lu2(SiO4)3 host.It is a promising candidate for application in white LED as a white light converter.
we developed a new silicate-based full-color phosphor Ba3Lu2(SiO4)3:Eu2+ through solid state reaction.The host crystal structure was isostructural with Ca3Y2(SiO4)3 instead of garnet-type.The phosphor absorbed near-ultraviolet light from 250 to 400 nm,which was very suitable for a color converter of white LED that used UV-LED as the primary light source.The photoluminescence peak wavelength of Ba3Lu2(SiO4)3:Eu2+ was about 461 nm and a shoulder peak was around 522 nm,which resulted from the 5d-4f transition of the Eu2+.The optimum concentration of Eu2+ was 3.45 mol.% of Ba2+ content in Ba3Lu2(SiO4)3 host.It is a promising candidate for application in white LED as a white light converter.
基金
Project supported by Natural Science Foundation of Jiangxi Province (2009GQC0042)
Foundation of Jiangxi Educational Committee (GJJ10153)
Major Science and Technology Project of Jiangxi Province (2010AZD00100)
Foundation of Jiangxi University of Science and Technology (Jxxjzd10007)