摘要
2-Ureido-4[1H]-pyrimidinone quadruple hydrogen-bonded assembly 1,1 containing N,N-dimethylaminophenyl moiety exhibits a sensitive response to fluoride anion and lead cation. Spectroscopic studies reveal that the presence of small amount of fluoride anions and lead cations can easily disassemble and intercalate 2-ureido- 4[ 1H]-pyri mi di none hydrogen-bonded supramolecular architectures.
2-Ureido-4[1H]-pyrimidinone quadruple hydrogen-bonded assembly 1,1 containing N,N-dimethylaminophenyl moiety exhibits a sensitive response to fluoride anion and lead cation. Spectroscopic studies reveal that the presence of small amount of fluoride anions and lead cations can easily disassemble and intercalate 2-ureido- 4[ 1H]-pyri mi di none hydrogen-bonded supramolecular architectures.
基金
Project supported by the National Natural Science Foundation of China (Nos. 20732007, 21002108 and 91024041), the Ministry of Science and Technology of China (Nos. 2007CB808004, 2007CB936001). and the Bureau for Basic Research of the Chinese Academy of Sciences.