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一个新的二维氰基桥连的混价铜Cu(Ⅰ)/Cu(Ⅱ)配位聚合物的合成、结构和性质研究 被引量:1

Synthesis structure and properties of a novel Copper(Ⅱ)-Copper(Ⅰ) mixed-valence polymer compound
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摘要 设计合成了一个CN-连接的稳定的Cu(I)/Cu(II)的混价配位聚合物。该化合物有非常奇特的三维空间结构,并且以光谱性质、电化学性质和磁学性质对它进行了表征。 A Cyano-bridged Copper(Ⅱ)-Copper(Ⅰ) mixed-valence polymer compound [Cu(Ⅰ)Cu(Ⅱ)(CN)3(py)3] 2n has been designed and synthesized.The compound has novel three-dimensional structure,which is characterized by spectroscopic electrochemistry and magnetic properties.
作者 白丽霞 刘欣
出处 《天津化工》 CAS 2011年第6期18-21,共4页 Tianjin Chemical Industry
基金 国家自然科学基金资助(批准号:20071020)
关键词 混价铜 配位聚合物 晶体结构 光谱 电化学 磁学性质 mixed-valence structure polymer compound spectroscopic electrochemistry magnetic
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