金属/SiO_2复合气凝胶催化剂对一氧化碳氧化的催化

Catalytic Oxidation of CO on M SiO_2 Aerogels Catalysts

采用溶胶－凝胶法和超临界干燥法制备了Ｃｕ／ＳｉＯ２ 和Ｃｏ／ＳｉＯ２ 气凝胶催化剂， 对其结构和形貌进行了ＸＲＤ、ＴＥＭ 和比表面分析， 并考察了其对ＣＯ氧化的催化性能。实验结果表明， 制得的Ｃｕ／ＳｉＯ２ 和Ｃｏ／ＳｉＯ２ 气凝胶催化剂均保留了气凝胶的纳米网络和高比表面积， 活性组份均匀地分散在纳米级二氧化硅气凝胶载体中， 对ＣＯ的氧化均表现出高的催化活性。

M SiO 2 aerogels catalysts(M = Cu or Co) are prepared by sol-gel process and supercritical drying. The resulting aerogels are characterized using transmission electron microscopy (TEM), XRD and nitrogen adsorption analysis. Their catalytic behavior for CO oxidation has been studied. The results indicate that Cu SiO 2 or Co SiO 2 catalysts have high catalytic activity at 100-400°C.