期刊文献+

铜/铝钎焊用Zn-Al钎料的电化学腐蚀性能研究 被引量:5

Research of Electrochemical Corrosive Characteristics of Zn-Al Solders for Cu/Al Brazing
下载PDF
导出
摘要 采用铸锭冶金法,在高频感应炉中制备了铜/铝钎焊用Zn-22Al钎料,通过浸泡腐蚀试验、电化学腐蚀试验对添加Mg元素的钎料的耐蚀性能进行了评价分析,并探讨了其腐蚀机理。研究结果表明,添加Mg元素可显著提高钎料基体的电极电位,从而显著提高钎料本身的耐腐蚀性能,并不会显著降低铜/铝接头的强度。加入Mg元素的Zn-22Al钎料,配合CsF-AlF3无腐蚀中温钎剂,采用高频感应加热钎焊连接铜/铝管,通过浸泡腐蚀试验后,仍可获得高剪切强度的接头。 Zn-Al solders used for Cu/Al brazing were prepared by ingot metallurgy method in high frequency induction furnace. The anti-corrosive properties of Zn-Al solders added with Mg were evaluated and analyzed by immersion tests, electrochemical corrosion measurements, and the corrosive mechanism was discussed. The results show that the electrode potential of the solders substrates can be significantly improved by the addition of Mg to greatly improve the anti-corrosive properties of solders, while it will not significantly reduce the shear strength of welding joint. Using the Zn-Al solder added with Mg and CsF-AlF3 flux, Al and Cu tubes can be brazed by high frequency brazing method without air leaking at high air pressure even after immersion tests.
出处 《热加工工艺》 CSCD 北大核心 2011年第23期14-16,共3页 Hot Working Technology
基金 广东省教育部产学研结合项目(2009B090300289)
关键词 铝/铜钎焊 Zn—Al钎料 电化学腐蚀 阳极极化 Cu/Al brazing Zn-Al solders electrochemical corrosion anodic polarization
  • 相关文献

参考文献8

二级参考文献29

  • 1苏文英,阎玉芹,叶赐麒.铝-铜火焰钎焊材料研究[J].北京工业大学学报,1994,20(4):45-51. 被引量:18
  • 2李劲风,张昭,郑子樵,谭澄宇,张鉴清.拉应力对7075铝合金的剥蚀及其电化学阻抗谱的影响[J].腐蚀科学与防护技术,2005,17(2):79-82. 被引量:14
  • 3曲文卿,董峰,齐志刚,庄鸿寿,孟伟.异种材料的连接[J].航天制造技术,2006(3):44-49. 被引量:35
  • 4马海军,李亚江,王娟.Al/Cu异种有色金属的真空钎焊工艺[J].焊接技术,2007,36(1):36-38. 被引量:26
  • 5HB5455-90,铝合金剥层腐蚀试验方法[S].
  • 6Buchheit R G,Morgan J P,Stoner G E.Electrochemical behavior of the TI (A12CuLi) intermetallic compound and its role in localized corrosion of Al-2%Li-3%Cu alloys[J].Corrosion,1994,50:120-131.
  • 7Najjar D,Magnin T,Warner T J.Influence of critical surface defects and localized competition between anodic dissolution and hydrogen effects during stress corrosion cracking of a 7050 aluminum alloy[J].Mater Sci Eng A,1997,A238(2):293-302.
  • 8Sinyavskii V S,Ulanova V V,Kalinin V D.On the mechanism of intergranualar corrosion of aluminum alloys[J].Protection of Metals,2004,40(5):537-546.
  • 9Ramgopal T,Gouma P I,Frankel G S.Role of grain boundary precipitates and solute-depleted zone on the intergranular corrosion of aluminum alloy 7150[J].Corrosion,2002,58(8):6R7-697.
  • 10Sinyavskii V S,Ulanova V V,Kalinin V D.On the mechanism intergranualar corrosion of aluminum alloys[J].Protection Metals,2004,40(5):537-546.

共引文献71

同被引文献28

  • 1张胜华,郭祖军.铜-铝复合材料的研究[J].中国有色金属学报,1995,5(4):128-132. 被引量:33
  • 2Lee Wonbae, Bang Kueksaeng, Jung Seungboo. Effects of intermetallic compound on the electrical and mechanical properties of friction welded Cu/AI bimetallic joint during annealing [J]. Journal of Alloys and Compounds,2005,390 (1-2):212-219.
  • 3Abbasi M, Karimi Taheri A, Saleh M T. Growth rate of intermetallic compounds in AI/Cu bimetal produced by cold roll welding process [J]. Journal of Alloys and Compounds, 2001,3199(1-2) :233-241.
  • 4Harutyunyan V S, Torossyan A R, Aivazyan A P. Deformations subgrain structure,dislocation arrangement and transition layer formation in Cu/AI coating deposited by mechanochemical technique [J]. Applied Surface Science, 2004,222(1-4): 43 -64.
  • 5黄红军,贾真,袁晓光,等.铜-铝-铜复合板导电特性的模拟[J].特种铸造及有色冶金,2007,27(5):354-356.
  • 6谢军,吴卫东,杜凯,等.Cu/AI微米级厚度薄膜扩散连接工艺及显微组织分析[J].原子能科学技术,2004,38(7):120.124.
  • 7胡赓祥,蔡殉,戎咏华.材料科学基础(第三版)[M].上海:上海交通大学出版社,2010.
  • 8张鹏,崔建忠,杜云慧,巴立民.钢-铝固液相复合中浸镀助焊剂的应用研究[J].金属学报,1997,33(8):869-873. 被引量:15
  • 9张红安,陈刚.铜/铝复合材料的固-液复合法制备及其界面结合机理[J].中国有色金属学报,2008,18(3):414-420. 被引量:57
  • 10陈康华,包崇玺,刘红卫.金属/陶瓷润湿性(下)[J].材料科学与工程,1997,15(4):27-34. 被引量:37

引证文献5

二级引证文献14

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部