期刊文献+

尖晶石型MAl_2O_4粉体的制备及光催化性能 被引量:1

Synthesis and Study on Photocatalytic Properties of Aluminate Spinel Powders
下载PDF
导出
摘要 以有机物前驱体法制备铝酸盐尖晶石MAl2O4(M为Cu,Zn),采用X-射线衍射、透射电镜等方法对试样进行表征.结果表明:700℃焙烧得ZnAl2O4,800℃焙烧得到CuAl2O4和微量CuO.在以甲基橙为降解物和100W汞灯辐照2h的光催化实验中,700℃焙烧ZnAl2O4粉体对甲基橙的脱色率为89.4%;而800℃的CuAl2O4对甲基橙的脱色率可以达到96.7%. In this paper, spinel-type aluminate photocatalysts MAl2O4 (M= Cu, Zn) were synthesized by organic precursor method. These samples were characterized by XRD, TEM, etc. It is found that ZnAl2O4 powders were synthesized at 700℃ and CuAl2O4 with little CuO at 800 ℃. The results show that the decolorizing efficiency of methyl orange can reach 89. 4% by using ZnAl2O4 powders synthesized at 700℃ and 96.7% by using CuA1204 powders synthesized at 800 ℃ under 2 hours illumination of 100W mercury lamp.
作者 骆凡 胡东红
出处 《泉州师范学院学报》 2011年第6期45-49,共5页 Journal of Quanzhou Normal University
关键词 ZNAL2O4 CuAl2O4 光催化 尖晶石 ZnAl2O4 CuAl2O4 photocatalysis spinel
  • 相关文献

参考文献23

  • 1FUJISHIMA A, HONDA K. Electrochemical photolysis of water at a semiconductor electrode[J]. Nature, 1972,238:37-38.
  • 2BHOWMCK M, SEMMENS M J. Ultraviolet Photooxidation for the destruction of VOCs in Air[J]. Water Res, 1994,28(11):2410- 2415.
  • 3FU H B,ZHANG L W, ZHU Y F, et al. Nanosized Bi2WO6 catalysts prepared by hydrothermal Synthesis and their photocatalytic proparties[J]. Applied Catalysis B: Environmental, 2006,66 (1/2) : 100-110.
  • 4陈旬,林平勇,史喜成,张忠良,谢志鹏,李朝晖.InOOH纳米晶的控制合成及其液相光催化性能[J].无机化学学报,2009,25(11):1917-1921. 被引量:5
  • 5BESSEKHOUAD Y, TRARI M. Photoeatalytic hydrogen production from suspension of spinel powders AMn2O4 (A=Cu and Zn)[J]. International Journal of Hydrogen Energy, 2002,27(4):357-362.
  • 6TANG J, ZOU Z, YIN J, et al. Photocatalytic degradation of methylene blue on Caln2 O4 under visible light irradiation[J]. Chemical Physics Letters, 2003,382(1/2) : 175-179.
  • 7YANG Y, JIANG Y S, WANG Y W, et al. Influences of sintering atmosphere on the formation and photocatalytie property of BaFe2O4 [J]. Materials Chemist ry and Physics, 2007,105 (2/3) : 154-156.
  • 8CAO X B, GU L, LAN X M, et al. Spinel ZnFe2 O4 nanoplates embedded with Ag clusters: preparation, characterization and photocatalytic application[J]. Materials Chemistry and Physics, 2007(106):175-180.
  • 9HOU X Y,FENG J, XU X D, et al. Synthesis and characterizations of spinel MnFe2O4 nanorod by seed-hydrothermal route[J]. Journal of Alloys and Compounds, 2010,491(1/2) : 258-263.
  • 10姜妍彦,李景刚,宁桂玲,王承遇.尖晶石型CuAl_2O_4纳米粉体的制备及其可见光催化性能[J].硅酸盐学报,2006,34(9):1084-1087. 被引量:26

二级参考文献72

  • 1刘锦宏,王丽,薛萍萍,温福昇,李发伸.纳米颗粒NiFe_2O_4的穆斯堡尔谱研究[J].兰州大学学报(自然科学版),2005,41(1):78-81. 被引量:3
  • 2李新勇,李树本,吕功煊.纳米尺寸铁酸锌半导体催化剂的表征及催化性能研究[J].分子催化,1996,10(3):187-193. 被引量:34
  • 3王禄,马伟,韩梅,孟长功.高效锂离子筛吸附剂MnO_2·0.5H_2O的软化学合成及吸附性能研究[J].化学学报,2007,65(12):1135-1139. 被引量:32
  • 4A. D. Mazzonia, M. A. Sainzb, A. Caballerob, E. F. Agliettia. Carbon coating and reaction on magnesiaalumina spinel [J]. Materials Chemistry and Physics 2002,101(1) :211-216
  • 5E. H. Walker Jr. ,J. W. Owens, M. Etienne, D. Walker. The novel low temperature synthesis of nanocrystalline MgAl2O4 spinel using "gel" precursors [J] . Materials Research Bulletin,2002,37(6) : 1041-1050
  • 6J. Parmentier, M. R. Plouet, S. Vilminot. Influence of the sol --gel synthesis on the formation of spinel MgAl2O4 [J]. Materials Research Bulletin, 1998,33 (11) : 1717-1724
  • 7M. Veith,S. Mathur,C. Mathur. New perspectives in the tailoring of hereto ( bi -- and tri-- ) metallic alkoxide derivatives. Polyhedron, 1998,17(5-- 6) :1005-1034
  • 8Watanabe T, Takirawa T, Honda K. J. Phys. Chem., 1977, 81:1845-1851.
  • 9Chen C, Zhao W, Zhao J C. Chem. Eur. J., 2004,111:1956-1965.
  • 10Wu T X, Liu G M, Zhao J C. J. Phys. Chem., 1998,102: 5845-5851.

共引文献67

同被引文献2

引证文献1

二级引证文献1

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部