期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

基于卟啉化合物的异质结有机太阳能电池 被引量：2

Bulk Heterojunction Solar Cell Based on Porphyrin Compounds
下载PDF
导出
摘要 采用混合溶剂制备了四苯基卟啉(TPP)及其铜配合物(TPPCu)和氯化对甲氧基四苯基铁卟啉(TMPPFeCl),将三种卟啉化合物和富勒烯的衍生物(PCBM)分别共混,制备异质结太阳能电池。器件结构是ITO/porphyrin∶PCBM/Al,研究此类电池的性能。结果显示基于TPP∶PCBM的器件性能最优,其短路电流密度(JSC)是0.98mA.cm-2,开路电压(VOC)是0.52V,填充因子(FF)为30.1%。TPP是三种卟啉化合物中最佳的给体材料。进而考察了TPP∶PCBM的不同浓度配比对器件性能的影响。TPP∶PCBM的最佳浓度配比为1∶1,增加或减少TPP的量都会使器件的短路电流和开路电压降低,对填充因子的影响不大。 Three kinds of porphyrins which can abbreviate as TPP,TPPCu and TMPPFeCl were s ynthesized by one-step method with mixed solvents.Then these porphyrin materia ls were used as donors to fabricate organic solar cells with PCBM as accepter by t he solution processing of spin-coating method.The structure is ITO/porphyrin∶ PCBM/Al.The photovoltaic characterizations of these devices were investigated. The device based on TPP∶PCBM shows the best performance with an open circuit vo ltage（VOC） of 0.52 V,a short circuit current（JSC） of 0. 98 mA·cm-2,and fill factor（FF） of 30.1%.Then the influence of differ ent weight ratio of TPP∶PCBM was researched.The best weight ratio of TPP∶PCB M is 1∶1.Increasing or decreasing the quatity of TPP would make JSC and VOC of the device deterioration and have little effect on the FF.
作者 张天慧 赵谡玲 朴玲钰 徐征 孔超
机构地区 北京交通大学光电子技术研究所 国家纳米科学中心
出处 《光谱学与光谱分析》 SCIE EI CAS CSCD 北大核心 2012年第1期157-161,共5页 Spectroscopy and Spectral Analysis
基金 国家自然科学基金项目(60978060) 北京市科委项目(Z090803044009001) 北京交通大学优秀博士生科技创新基金项目(141107522)资助
关键词 卟啉 异质结 浓度比 Porphyrin Heterojunction Weight ratio
分类号 O649.5 [理学—物理化学]
  • 相关文献

参考文献16

  • 1林鹏,张志峰,熊德平,张梦欣,王丽.有机太阳能电池研究进展[J].光电子技术,2004,24(1):55-60. 被引量：8
  • 2Dudkowiak A, Teslak E, Habdas J. J. Mol. Struct., 2006, 93: 792.
  • 3Zheng W, Shan N, Xu L, et al. Dyes Pigments, 2008, 77: 153.
  • 4Meunier B. Chem. Rev., 1992, 92: 1411.
  • 5De Silva A P, Gunaratne H Q N, Gunnlaugsson T, et al. Chem. Rev., 1997, 97: 1515.
  • 6Baldo M A, O’Bren D F, You Y, et al. Nature, 1998, 395: 151.
  • 7Campbell W M, Burrell A K, Officer D L, et al. Coord. Chem. Rev., 2004, 248: 1363.
  • 8Belcher W J, Wagner K I, Dastoor P C. Sol. Energy Mater. Sol. Cells., 2001, 91: 447.
  • 9李忠芳,王素文,王纪孝,王亚权,王宇新.过渡金属离子为模板的卟啉过渡金属配合物的合成研究[J].无机化学学报,2003,19(7):691-698. 被引量：7
  • 10Sun E J, Cheng X L, Wang D. Solid State Sci., 2007, 9: 1061.

二级参考文献50

  • 1Hou J H,Tan Z A,Yan Y,et al.Synthesis and photovohaic properties of two-dimensional conjugated polythiophenes with bi(thienylenevinylene)side chains[J].J Am Chem Soc,2006,128(14):4 911-4 916.
  • 2Yang X N,Loos J,Veenstra S C,et al.Nanoscale morphology of high-performance polymer solar cells[J].Nano Lett,2005,5(4):579-583.
  • 3Li G,Shrotriya V,Huang J S,et al.High-efficiency solution processable polymer photovoltaic cells by self-organization of polymer blends[J].Nat Mater,2005,4(11):864-868.
  • 4Cravino A,Roquet S,Aleveque O,et al.Triphenylamine-oligothiophene conjugated systems as organic semiconductors for opto-electronics[J].Chem Mater,2006,18(10):2 584-2 590.
  • 5Roquet S,Cravino A,Leriche P,et al.Triphenylamine-thienylenevinylene hybrid systems with internal charge transfer as donor materials for heterojunction solar cells[J].J Am Chem Soc,2006,128(10):3 459-3 466.
  • 6Cravino A,Roquet S,Leriche P,et al.A star-shaped triphenylamine pi-conjugated system with internal chargetransfer as donor material for hetero-junction solar cells[J].Chem Commun,2006,(13):1 416-1 418.
  • 7Ashe A J,Kampf J W,Saris P M.The reaction of sulfur with dilitio compounds.The syntheses and structures of phenanthro[1,10-cd]-1,2-dithiole and phenanthro[4,5-cde][1,2]dithiin[J].Heteroat Chem,1994,5:113-119.
  • 8Tesmer M,Vahrenkamp H.Sterically fixed dithiolate ligands and their zinc complexes:Derivatives of 1,8-dimercaptonaphthalene[J].Eur J Inorg Chem,2001,(5):1 183-1 188.
  • 9Zaitsev V,Rosokha S V,Head-Gordon M,et al.Steric modulations in the reversible dimerizations of phenalenyl radicals via unusually weak carbon-centered pi-and sigma-bonds[J].J Org Chem,2006,71(2):520-526.
  • 10Hancock J M,Gifford A P,Zhu Y,et al.n-Type conjugated oligoquinoline and oligoquinoxaline with triphenylamine endgroups:Efficient ambipolar light emitters for device applications[J].Chem Mater,2006,18(20):4 924-4 932.

共引文献13

同被引文献43

  • 1Dennler G,Scharber M C,Brabec C J.Polymer-FullereneBulk-Heterojunction Solar Cells [ J ].Adv.Mate.,2009,21(13):1 323-1 338.
  • 2Chu T,Lu J,Beaupre S,et al.Bulk Heterojunction Solar Ceils Using Thieno[ 3,4-c]pyrrole-4,6-dione and Dithieno [ 3,2-b:2',3'-d ]silole Copolymer with a Power Conversion Efficiency of 7.3 % [ J ].J.Am.Chem.Soc.,2011,133(12):4 250-4 253.
  • 3Chang J A,Rhee J H,Im S H,et al.High-Performance Nanostructured Inorganic Organic Heterojunction Solar Cells [J].Nano Lett.,2010,10(7):2 609-2 612.
  • 4Varotto A,Nam C Y,Radivojevic I,et al.Phthalocyanine Blends Improve Bulk Heterojunction Solar cells [ J ].J.Am.Chem.Soc.,2010,132(8):2 552-2 554.
  • 5Ajimsha R S,Jayaraj M K,Kukreja L M.Heterojunction Diodes Grown by Pulsed Laser Deposition at Different Oxygen Pressures[J].J.Electron.Mater.,2008,37(5):770-775.
  • 6Zhang L,Leburton J.Modeling of the Transient Characteristics of Heterojunction Bipolar Transistor Lasers [ J ].Quantum E-lectronics,2009,45(4):359-366.
  • 7Cinchett M,Heimer K,Wiistenberg J P,et al.Determination of spin injection and transport in a ferromagnet/organic semi-conductor heteroiunction by two-Dhoton ohotoemission[J].Nature Materials.2009.8:115-119.
  • 8Kim W,Tachikawa T,Majima T,et al.Photocatalysis of Dye-Sensitized TiO2 Nanoparticles with Thin Overcoat of Al2 O3:Enhanced Activity for H2 Production and Dechlorination of CCl4 [ J ].J.Phys.Chem.C,2009,113(24):10 603-10 609.
  • 9Desai U V,Xu C,Wu J,et al.Hybrid TiO2-SnO2 Nanotube Arrays for Dye-Sensitized Solar Cells [ J ].J.Phys.Chem.C,2013,117(7):3 232-3 239.
  • 10Bouele J,Aekermann J.Solid-state dye-sensitized and bulk heterojunetion solar cells using TiO2 and ZnO nanostrue-tures:recent progress and new concepts at the borderline [ J ].Polymer International,2012,61(3):355-373.

引证文献2

二级引证文献5

光谱学与光谱分析
2012年 第1期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部