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壳聚糖固载β-环糊精的制备及其与二茂铁和二茂铁衍生物的主客体作用

Preparation of β-CD-grafted-chitosan and investigation of its host-guest interaction with ferrocene and derivatives
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摘要 以壳聚糖为母体,合成了携带β-环糊精侧基的壳聚糖大分子主体化合物(CDCS).通过红外光谱、X-射线衍射和浓硫酸降解等方法对CDCS进行了表征;并利用X-射线衍射和紫外-可见吸收光谱等分析方法研究了CDCS分别与二茂铁和二茂铁苯酮酸的主客体相互作用.结果表明,带有二茂铁基团的客体与壳聚糖主体化合物侧链上固载的环糊精主体确实发生了主客体相互作用. The β-CD-grafted-chitosan（CDCS） has been synthesized with chitosan as matrix.The structure of the product has been determined and characterized by FT-IR,XRD,and H2SO4 degradation methods.Further more,the host-guest interaction of CDCS with ferrocene and ferrocenylcarbonyl benzoic acid has been systematically studied by employing XRD and UV techniques.As expected,the guest compounds containing ferrocene interact with the β-CD-labeled polymer backbone.
作者 姜明伟 申娟 邱雄鹰 郭成功 王彩旗
机构地区 中国科学院研究生院化学与化学工程学院
出处 《中国科学院研究生院学报》 CAS CSCD 北大核心 2012年第1期32-37,共6页 Journal of the Graduate School of the Chinese Academy of Sciences
基金 国家自然科学基金(20604033) 中国科学院研究生院院长基金资助
关键词 二茂铁 环糊精 主客体作用 壳聚糖 自组装 ferrocene； cyclodextrin； host-guest interanction； chitosan； self-assembly
分类号 O636.1 [理学—高分子化学]
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参考文献17

  • 1Park J H, Kwon S, Nam J-O, et al. Self-assembled nanoparticles based on glycol chitosan bearing 5/3-cholanic acid for RGD peptide delivery[ J]. Journal of Controlled Release, 2004, 95 (3) : 579-588.
  • 2Krauland A H, Alonso M J, Chitosan/cyclodextrin nanopartlcles as macromoleeular drug delivery system [ J ]. International Journal of Pharmaceutics, 2007, 340 : 134-142.
  • 3Kim T H, Park I K, Nah J W, et al. Galactosylated ehitosan/DNA nanopartieles prepared using water-soluble chitosan as a gene carrier [ J]. Biomaterials, 2004, 25 (17) : 3783-3792.
  • 4Harada A. Cyclodextrin-based molecular machines[ J]. Accounts of Chemical Research, 2001, 34: 456-464.
  • 5Rachel A V, Rinaudo M. New supramolccular assemblies of a cyclodextrin-grafted chitosan through specific complexation [ J ]. Macromolecules, 2002, 35: 7955-7962.
  • 6Brunsveld L, Folmer B J, Meijer B, et al. Supramolecular polymers[J]. Chem Rev, 2001, 101 : 4071-4098.
  • 7Hasegawa Y, Miyauehi M, Takashima Y, et al. Supramolecular polymers from β-cyclodextrin dimmer linked by poly( ethylene glycol) and guest dimmers[J]. Macronaolecules, 2005, 38: 3724-3730.
  • 8Ohga K, Takashima Y, Takahashi H, et al. Preparation of supramolecular polymers from a eyclodextfin dimmer and ditopic guest molecules: control of structure by linker flexibility[J]. Macromolecules, 2005, 38 : 3897-5904.
  • 9Prabaharan M, Mano J F. Chitosan derivatives bearing cyclodextrin cavitiesas novel adsorbent matrices [ J ]. Carbohydrate Polymers, 2006, 63: 153-166.
  • 10Sashiwa H, Aiba S. Chemically modified chitin and chitosan as biomatefials[ J]. Progress in Polymer Science, 2004, 29: 887-908.

二级参考文献38

  • 1康澍,陈湧,史珺,马玉红,刘育.全甲基及其多胺修饰环糊精与牛血清白蛋白的相互作用[J].高等学校化学学报,2007,28(3):458-461. 被引量：11
  • 2Liu Wan-yi, Xie Tong, Liang Yong-min, et al. J. Organomet. Chem. , 2001, 627 ( 1 ) : 93.
  • 3Harada A, Hu Y, Yamamoto S, et al. J. Chem. Soc. Dalton. Trans., 1988, 3: 729.
  • 4Benesi HA, Hilderbrand J H. J. Am. Chem. Soc., 1949, 71: 2703.
  • 5Ohga K. , Takashima Y. , Takahashi H, , et al.. Macromolecules[ J] , 2005, 38(14) : 5897--5904.
  • 6Takahashi H. , Takashima Y. , Yamaguchi H. , et al.. Org. Chem. [J] , 2006, 71(13) : 4878---4883.
  • 7Balzani V, , Credi A. , Venturi M. ; Translated by TIAN He(田禾), WANG Li-Min( 王利民). Molecular Devices and Machines(分子器件与分子机器) [ M]. Seijing: Chemical Industry Press, 2005.
  • 8LIU Yu(刘育) , YOU Chang-Cheng(尤长城) , ZHANG Heng-Yi (张衡). Supramolecular Chemistry -- Molecular Recognition and Assembly of Synthetic Receptors(超分子化学--合成受体分子识别与组装)[M].Tianjin: Nankai University Press, 2001:167--306.
  • 9Tamaru S. , Takeuchi M. , Sano M. , et al.. Angew. Chem. Int. Ed. [J]. 2002, 41:853--856.
  • 10Xue P. C. , Lu R. , Huang Y. , et al.. Langmuir[ J]. 2004, 20:6470--6475.

共引文献18

中国科学院研究生院学报
2012年 第1期

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