摘要
合成了新型吡唑基P,N-双齿配体3,5-二甲基-4-(2-二苯基膦乙基)吡唑(L),成功应用于构建钌(Ⅱ)配合物[Ru(η5-C5H5)Cl(PPh3)](L),配体中磷原子作为单齿配体配位到钌金属上形成中性金属配合物,并通过核磁共振波谱对配合物溶液结构进行了测定.
A new type of pyrazolyl-based P,N-bidentate ligand 4-(2-Diphenyl phosphanyl-ethyl)-3,5-dimethyl-lH-pyrazole (L) was successfully synthesized and applied in the construction of Ruthenium (II) complex [Ru(r/s-C5 H5 )CI(PPh3)] (L) in which the ligand exhibits k^1 P-coordination to the metal center. Ligand and Ruthenium(II) complex were characterized by NMR.
出处
《青岛理工大学学报》
CAS
2011年第6期8-11,共4页
Journal of Qingdao University of Technology
基金
山东省自然科学基金资助项目(ZR2010BQ015)
泰山学者建设工程专项经费资助