摘要
选用三氟乙酸铜的盐溶液,以邻菲罗啉为配体,首次合成了三氟乙酸铜的邻菲罗啉配合物,并选用乙醇/乙酸乙酯混合溶剂,水浴培养得到蓝色块状晶体。利用高斯软件对其可能结构进行了模拟计算,并通过红外表征证实了模拟结果的准确性,确定了合成配合物的结构式为[Cu(C12H8N2)2H2O](CF3COO)2。
[Cu（C12H8N2）2H2O]（CF3COO）2 was first synthesized by the salt of three fluorine copper and the ligand of 1,10-Phenanthroline,and its blue massive crystals was obtained by water bath training in the ethanol/ethyl acetate mixed solvent.The possible structures were simulated by the Gaussian software,and the accuracy of the simulation result was confirmed through the infrared characterization.
出处
《青岛科技大学学报（自然科学版）》
CAS
2011年第6期576-579,共4页
Journal of Qingdao University of Science and Technology:Natural Science Edition
关键词
三氟乙酸铜
邻菲罗啉
晶体配合物
高斯模拟
three fluorine copper
1
10-phenanthroline
crystal complexes
gaussian simulation
