聚合金属酞菁的合成及研究进展

Synthesis and Research Progress on Metal Polyphthalocyanine

介绍了聚合金属酞菁的特性,因其具有大的共轭结构和较高的化学稳定性,和芳香环既有电子给体的特性、电子受体的特性,因此表现出良好的电催化氧还原活性;聚合金属酞菁作为催化剂,能使氧化反应在低温下高效进行,作为敏化剂,能有效提高光电转换效率。阐述了国内外聚合金属酞菁的研究方法和应用前景,提出了自由设计聚合金属酞菁分子结构,拓展了其应用领域。

Metal polyphthalocyanine showed good electrical catalytic oxygen reduction activities for its conjugate structure,high chemical stability and own characteristics of electron donor and electron acceptor.As catalyst,metal polyphthalocyanine could make the oxidation reaction in the low temperature efficient,and as sensitizer,metal polyphthalocyanine could improve photoelectric conversion efficiently.Research method and application prospect were reviewed in the end of the paper.Proposed free design polymerization metal polyphthalocyanine molecular structure which expanded its application fields.