摘要
在无氧环境下对黑液进行快速热解,获得液态的生物油和由碱金属盐类与炭结合组成的焦炭。结果表明:黑液快速热解将黑液中的木素转化为含丰富的酚类化合物的生物油,有利于黑液的资源化利用;生物油的GC-MS分析表明,其主要由10种酚类、6种酮类及5种不饱和烃类组成,其中酚类相对百分含量高达88.02%,是代替苯酚合成酚醛树脂胶黏剂的理想原料;理论上可以通过快速热解高效回收碱。
Bio-oil and coke which is composed of char and alkali are obtained through the pyrolysis of black liquor. The results showed that： fast pyrolysis is conducive to the comprehensive utilization of black liquor, turning the lignin of black liquor into bio- oil that contains abundant phenols. GC-MS analysis proves that bio-oil is mainly composed of ten kinds of phenols, six types of ketones and five unsaturated hydrocarbons, including percentage content of phenols up to 88.02%. It is the best alternative of phenol to synthetic phenolic resin. Theoretically, alkali can be efficiently recovered by fast pyrolysis.
出处
《纸和造纸》
北大核心
2012年第1期51-53,共3页
Paper and Paper Making
基金
中央高校基本科研业务费专项资金资助(GD2010-3)
关键词
黑液
热解
生物油
black fiquor
pyrolysis
bio-oil
