Poly(2-acetoxyethyl methacrylate)/polystyrene latex interpenetrating polymer networks with well-defined phase-separated structure 被引量：1

Poly(2-acetoxyethyl methacrylate)/polystyrene latex interpenetrating polymer networks with well-defined phase-separated structure

原文传递

导出

摘要 A series of poly（2-acetoxyethyl methacrylate）/polystyrene（PAEMA/PS） latex interpenetrating polymer networks（LIPNs） were prepared by seeded soap-free emulsion polymerization of styrene on the crosslinked PAEMA seed particles using an oil-soluble initiator.These PAEMA/PS LIPNs showed a well-defined phase-separated structure with PS phase dispersing in continuous PAEMA phase.The domain size of PS phase was found to depend on the crosslinking degree of PAEMA seed particles and the amount of second-stage styrene monomer. A series of poly（2-acetoxyethyl methacrylate）/polystyrene（PAEMA/PS） latex interpenetrating polymer networks（LIPNs） were prepared by seeded soap-free emulsion polymerization of styrene on the crosslinked PAEMA seed particles using an oil-soluble initiator.These PAEMA/PS LIPNs showed a well-defined phase-separated structure with PS phase dispersing in continuous PAEMA phase.The domain size of PS phase was found to depend on the crosslinking degree of PAEMA seed particles and the amount of second-stage styrene monomer.

作者 Tao Wang Shan Shi Li Na Bian Li Min Zhou Li Qun Zhao

机构地区 Key Laboratory of Applied Technology of Polymer Materials Department of Production Science and Technology

出处《Chinese Chemical Letters》 SCIE CAS CSCD 2011年第12期1505-1508,共4页 中国化学快报（英文版）

基金 supported by National Natural Science Foundation of China(No.50943028) Scientific Research Foundation for the Returned Overseas Chinese Scholars,State Education Ministry

关键词 PHASE-SEPARATION IPN Seeded soap-free emulsion polymerization CROSSLINKING PARTICLE Phase-separation IPN Seeded soap-free emulsion polymerization Crosslinking Particle

分类号 TQ317 [化学工程—高聚物工业] TS943.42 [轻工技术与工程—服装设计与工程]

引文网络
相关文献

参考文献14

1N. Nemirovski, M.S. Silverstein, M. Narkis, Polym. Adv. Techuol. 7 (1996) 247.
2Y. Chert, D. Ding, Z.Q. Mao, Y.F. He, Y. Hu, W. Wu, X.Q. Jiang, Biomacromolecules 9 (2008) 2609.
3S.C. Angadi, L.S. Manjeshwar, T.M. Aminabhavi, Ind. Eng. Chem. Res. 50 (2011) 4504.
4W.F. Zhao, J.Y. Huang, B.H. Fang, et al. J. Membr. Sci. 369 (2011) 258.
5Y.J. Lee, I.W. Cheong, J.Fl. Yeum, et al. Macromol. Res. 18 (2010) 208.
6Z.M. Xing, C.L. Wang, J. Yah, et al. Colloid Polym. Sci. 288 (2010) 1723.
7J.A. Manson, L.H. Sperling, Polymer Blends and Composites, Plenum Press, New York, 1976, Chapter 8.
8S. Shi, S. Kuroda, S. Tadaki, et al. Polymer 43 (2002) 7443.
9S. Shi, L.M. Zhou, T. Wang, et al. J. Appl. Polym. Sci. 120 (2011) 501.
10S. Shi, T. Wang, Y.T. Tang, et al. Chin. Chem. Lett. (2011), doi:10.1016/j.cclet.2011.04.018.