期刊文献+

Surface and Hydrogen Sorption Characteristics of Various Activated Carbons Developed from Rat Coal Mine (Zonguldak) and Anthracite 被引量:4

Surface and Hydrogen Sorption Characteristics of Various Activated Carbons Developed from Rat Coal Mine (Zonguldak) and Anthracite
下载PDF
导出
摘要 Activated carbon samples were developed from coal samples obtained from a coal mine, rat (Zonguldak, Turkey) and anthracite (Siberia, Russia), applying pyrolysis in a temperature range of 600-900 ℃ under N2 flow, and activation using chemical agents such as KOH, NH4Cl, ZnCl2 at 650 ℃. Nitrogen adsorption at low temperature (77 K) was used to characterize the activated carbon samples, and their pore structure properties including pore volume, pore diameter and pore size distribution were determined by means of the t-plots and DFT methods. The surface area values were higher for rat coal samples than for anthracite one, and for the rat coal samples treated with KOH + NH4Cl + ZnCl2 at 650 °C [Rat650(2)] there are highest surface area and total pore volume, 315.6 m2·g^-1 and 0.156 ml·g^-1, respectively. The highest value of the hydrogen sorption capacity was found as 0.71% (by mass) for the rat coal sample obtained by KOH + ZnCl2 treatment at 650 °C [Rat650(1)]. 激活的碳样品从从一个煤矿获得的煤样品被开发,老鼠(Zonguldak,土耳其) 并且白煤(西伯利亚,俄国) ,在 600900
出处 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2011年第6期931-937,共7页 中国化学工程学报(英文版)
基金 provided by the project DPT2002K120640 funded by State Planning Organization (DPT), Turkey
关键词 coal ANTHRACITE activated-carbon adsorption PYROLYSIS chemical activation nitrogen sorption hy-drogen sorption 氢氧化钾 无烟煤 活性炭 表面积 大鼠 吸附特性 煤矿 孔隙结构特性
  • 相关文献

参考文献18

  • 1Zielinski, M., Wojcieszak, R., Monteverdi, S., Mercy, M., Bettahar, M.M., "Hydrogen storage in nickel catalysts supported on activated carbon", lnt. J. Hydrogen Energy, 32, 1024-1032 (2007).
  • 2Villacafias, F., Pereira, M.F.R., Orfao, J.J.M., Figueiredo, J.L., "Ad- sorption of simple aromatic compounds on activated carbons", J. Colloidlnterf Sci., 293, 128 136 (2006).
  • 3Monge, J.A., Martinez, M.C.R., "Upper limit of hydrogen adsorp- tion on activated carbons at room temperature: A thermodynamic approach to understand the hydrogen adsorption on microporous carbons", Micropor. Mesopor. Mater., 112, 510-520 (2008).
  • 4Anion, A., Lafuente, E., Urriolabeitia, E., Navarro, R., Benito, A.M., Maser, W.K., Mart'mez, M.T., "Preparation of palladium loaded carbon nanotubes and activated carbons for hydrogen sorption", J. Alloys Compounds, 436, 294-297 (2007).
  • 5Hayashi, J., Muroyama, K., Gomes, V.G., Watkinson, A.P., "Fractal dimensions of activated carbons prepared from lignin by chemical activation", Carbon, 40, 617-636 (2002).
  • 6Xia, K., Gao, Q., Wu, C., Song, S., Ruan, M., "Activation, charac- terization and hydrogen storage properties of the mesoporous carbon CMK-3", Carbon, 45, 1989-1996 (2007).
  • 7Armandi, M., Bonelli, B., Arean, C.O., Garrone, E., "Role of mi- croporosity in hydrogen adsorption on templated nanoporous car- bons", Micropor. Mesopor. Mater., 112, 411-418 (2008).
  • 8Wong-Foy, A.G., Matzger, A.J., Yaghi, O.M., "Exceptional H2 satu- ration uptake in microporous metal-organic frameworks", J. Am. Chem. Soc., 128, 3494-3495 (2006).
  • 9Dinca, M., Dailly, A., Liu, Y., Brown, C.M., Neumann, D.A., Long, J.R., "Hydrogen storage in a microporous metal-organic framework with exposed Mn2+ coordination sites", J. Am. Chem. Soc., 128, 16876-16883 (2006).
  • 10Swesi, Y., Kerleau, E, Pitault, I., Heurtaux, F., Ronze, D., "Purifica- tion of hydrogen from hydrocarbons by adsorption for vehicles ap- plication", Sep. Purif. Teehnol., 56, 25-37 (2007).

同被引文献46

引证文献4

二级引证文献19

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部