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Ammonia volatilization and availability of Cu,Zn induced by applications of urea with and without coating in soils

Ammonia volatilization and availability of Cu,Zn induced by applications of urea with and without coating in soils
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摘要 Ammonia volatilization and the distribution of Cu and Zn were investigated in two types of soil treated with coated and uncoated urea.The rate of ammonia volatilization in two weeks after fertilizing with coated urea was 8% in soil 1 (soil derived from river alluvial deposits in Dongting Lake Plain) and 5.15% in soil 2 (red soil derived from quaternary red clay),about half the rates observed when fertilizing with common urea,implying that the hydrolysis speed of the coated urea was lower than for common urea,and that the coated urea can increase nitrogen use efficacy.As for the availability of Cu and Zn,their concentrations decreased in the first week after fertilization,and then increased,which was contrary to the effect of treatment on soil pH.For example,when the pH was 7.99,there was 0.79mg/kg exchangeable Cu and 0.85mg/kg exchangeable Zn in the soil derived from river alluvial deposits in Dongting Lake Plain.However,the concentrations of exchangeable Cu and Zn were generally lower for the common urea treatments than those with the coated urea because the peak pH for the common urea treatment was greater.The concentrations of these elements correlated well with pH in the range 4–8 in second order polynomial fits. Ammonia volatilization and the distribution of Cu and Zn were investigated in two types of soil treated with coated and uncoated urea.The rate of ammonia volatilization in two weeks after fertilizing with coated urea was 8% in soil 1 (soil derived from river alluvial deposits in Dongting Lake Plain) and 5.15% in soil 2 (red soil derived from quaternary red clay),about half the rates observed when fertilizing with common urea,implying that the hydrolysis speed of the coated urea was lower than for common urea,and that the coated urea can increase nitrogen use efficacy.As for the availability of Cu and Zn,their concentrations decreased in the first week after fertilization,and then increased,which was contrary to the effect of treatment on soil pH.For example,when the pH was 7.99,there was 0.79mg/kg exchangeable Cu and 0.85mg/kg exchangeable Zn in the soil derived from river alluvial deposits in Dongting Lake Plain.However,the concentrations of exchangeable Cu and Zn were generally lower for the common urea treatments than those with the coated urea because the peak pH for the common urea treatment was greater.The concentrations of these elements correlated well with pH in the range 4–8 in second order polynomial fits.
出处 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2012年第1期177-181,共5页 环境科学学报(英文版)
基金 supported by the National Natural Science Foundation of China (No. 30770389) the Hunan Province Science and Technology Project (No. 2009FJ3156)
关键词 ammonia volatilization coated urea SOIL metal element ammonia volatilization coated urea soil metal element
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