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Iron-mediated cross dehydrogenative coupling(CDC) of terminal alkynes with benzylic ethers and alkanes 被引量：6

Iron-mediated cross dehydrogenative coupling(CDC) of terminal alkynes with benzylic ethers and alkanes
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摘要 Iron-mediated sp-sp3 C-C bond formation through the cross dehydrogenative coupling(CDC) of terminal alkynes with benzylic ethers or alkanes has been developed.The inexpensive iron salt is used as the catalyst to make this transformation environmentally benign.Iron-mediated sp-sp3 C-C bond formation through the cross dehydrogenative coupling(CDC) of terminal alkynes with benzylic ethers or alkanes has been developed.The inexpensive iron salt is used as the catalyst to make this transformation environmentally benign. Iron-mediated sp-sp3 C-C bond formation through the cross dehydrogenative coupling（CDC） of terminal alkynes with benzylic ethers or alkanes has been developed.The inexpensive iron salt is used as the catalyst to make this transformation environmentally benign.Iron-mediated sp-sp3 C-C bond formation through the cross dehydrogenative coupling（CDC） of terminal alkynes with benzylic ethers or alkanes has been developed.The inexpensive iron salt is used as the catalyst to make this transformation environmentally benign.
作者 XIANG Shi-Kai ZHANG Bo ZHANG Li-He CUI YuXin JIAO Ning
机构地区 State Key Laboratory of Natural and Biomimetic Drugs Shanghai Key Laboratory of Green Chemistry and Chemical Processes
出处 《Science China Chemistry》 SCIE EI CAS 2012年第1期50-54,共5页 中国科学（化学英文版）
基金 supported by Peking University,the National Natural Science Foundation of China(20872003) National Basic Research Program of China(973 program)(2009CB825300)
关键词 末端炔烃 脱氢偶联 CDC 铁盐 烷烃 苄醚 介导 催化剂 iron cross dehydrogenative coupling terminal alkynes benzylic ethers
分类号 O623.124 [理学—有机化学] TE646 [石油与天然气工程—油气加工工程]
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Science China Chemistry
2012年 第1期

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