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Electrochemical Performance and ex situ Analysis of ZnMn2O4 Nanowires as Anode Materials for Lithium Rechargeable Batteries 被引量:7

Electrochemical Performance and ex situ Analysis of ZnMn2O4 Nanowires as Anode Materials for Lithium Rechargeable Batteries
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摘要 一个维的 ZnMn2O4 nanowires 在李作为阳极材料被准备了并且调查可充电的电池。在宽度的大约 15 nm 和在长度的 500 nm 显示出的高度水晶的 ZnMn2O4 nanowires 大约 650 mAh 獲獥 ? 的一个高特定的能力 ? 肐? 肐? One-dimensional ZnMn2O4 nanowires have been prepared and investigated as anode materials in Li rechargeable batteries. The highly crystalline ZnMn2O4 nanowires about 15 nm in width and 500 nm in length showed a high specific capacity of about 650 mAh.g-1 at a current rate of 100 mA.g-1 after 40 cycles. They also exhibited high power capability at elevated current rates, i.e., 450 and 350 mAh.g 1 at current rates of 500 and 1000 mA.g 1, respectively. Formation of Mn3O4 and ZnO phases was identified by ex situ X-ray diffraction (XRD) and transmission electron microscopy (TEM) studies after the initial discharge-charge cycle, which indicates that the ZnMn2O4 phase was converted to a nanocomposite of Mn3O4 and ZnO phases immediately after the electrochemical conversion reaction.
出处 《Nano Research》 SCIE EI CAS CSCD 2011年第5期505-510,共6页 纳米研究(英文版)
关键词 电化学性能 负极材料 纳米线 锂离子电池 可充电锂电池 透射电子显微镜 四氧化三锰 X射线衍射 Energy storage, lithium rechargeable battery, anode, ZnMn204, nanowire
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