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Preparation, Characterization, and Electrocatalytic Performance of Graphene-Methylene Blue Thin Films 被引量:2

Preparation, Characterization, and Electrocatalytic Performance of Graphene-Methylene Blue Thin Films
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摘要 我们向接枝汇报一个一般方法到 graphene 上,通过简单沉浸的薄电影电极处理的芳香的分子。大区域的 electroactive graphene 有甲又蓝色(MB ) 的薄电影 grafted 为菸碱腺嘌 dinucleotide (NADH ) 的氧化作为 electrocatalytic 电极被开发了。NADH 的氧化开始从 ? 0.08 V (对 Ag/AgCl ) 在 graphene-MB 薄电影电极,与一个 Ti 金属电极相比在过电位显示出 530 mV 的减少。薄电影有由于他们支持 NADH 电子转移反应的能力在生物传感器和 biofuel 房间答应应用程序的 graphene-MB。 We report a general method to graft aromatic molecules onto graphene thin film electrodes through a simple immersion process. Large-area electroactive graphene thin films grafted with methylene blue (MB) have been developed as electrocatalytic electrodes for the oxidation of β-nicotinamide adenine dinucleotide (NADH). The oxidation of NADH starts from -0.08 V (vs. Ag/AgC1) at the graphene-MB thin film electrodes, showing a decrease of 530 mV in overpotential compared to a Ti metal electrode. The graphene-MB thin films have promising applications in biosensors and biofuel cells due to their ability to promote NADH electron transfer reaction.
出处 《Nano Research》 SCIE EI CAS CSCD 2011年第1期124-130,共7页 纳米研究(英文版)
关键词 薄膜电极 亚甲蓝 电催化性能 石墨 烟酰胺腺嘌呤二核苷酸 制备 表征 NADH Graphene, electrocatalysis, methylene blue, β-nicotinamide adenine dinucleotide (NADH)
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  • 8杨怀成,魏万之,曾金祥,刘晓颖,王莹,杨明华.烟酰胺腺嘌呤二核苷酸的聚亚甲基蓝/单壁碳纳米管修饰电极差分脉冲伏安法检测[J].分析测试学报,2008,27(2):135-138. 被引量:8
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