期刊文献+

A highly efficient transacetalization of 2-formylpyrrole acetals in alkaline media

A highly efficient transacetalization of 2-formylpyrrole acetals in alkaline media
原文传递
导出
摘要 The reaction of 2-formylpyrrole acetals with sodium alkoxide in alcohols at reflux temperature smoothly proceeded to generate corresponding transacetalization products in nearly quantitative yields.A plausible mechanism involving the formation of a highly reactive intermediate azafulvene species was proposed to explain the observed transformation. The reaction of 2-formylpyrrole acetals with sodium alkoxide in alcohols at reflux temperature smoothly proceeded to generate corresponding transacetalization products in nearly quantitative yields.A plausible mechanism involving the formation of a highly reactive intermediate azafulvene species was proposed to explain the observed transformation.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2012年第1期33-36,共4页 中国化学快报(英文版)
基金 The Ministry of Education of The People's Republic of China Department of education of Jiangxi Province Jiangxi Provincial Natural Science Foundation for financial support
关键词 2-Formylpyrrole acetal Transacetalization Sodium alkoxide 2-Formylpyrrole acetal Transacetalization Sodium alkoxide
  • 相关文献

参考文献12

  • 1T.W. Greene, EG.M. Wuts, Protective Groups in Organic Chemistry, Wiley, New York, 1999, p. 297.
  • 2A.B. Smith, T. Bosanac, K. Basu, J. Am. Chem. Soc. 131 (2009) 2348.
  • 3A. Piasecki, B. Burczyk, A. Sokolowski, U. Kotlewska, Synth. Commun. 26 (1996) 4145.
  • 4L. Lemiegre, F. Lesetre, J.C. Combret, J. Maddalumo, Tetrahedron 60 (2004) 415.
  • 5B.P. Bandgar, N.S. Joshi, S.V. Bettigeri, Monatsh. Chem. 138 (2007) 67.
  • 6M. Sulu, L.M. Venanzi, Helv. Chim. Acta 84 (2001) 898.
  • 7N.K. Kochetkov, E.E. Nifantyev, A.N. Nesmeyanov, Russ. Chem. Bull. 6 (1957) 977.
  • 8W.E. Noland, G. Pardi, J. Heterocycl. Chem. 42 (2005) 1149.
  • 9K.A. Memoli, J. Heterocycl. Chem. 44 (2007) 927.
  • 10A.D. Abell, B.K. Nabbs, A.R. Battersby, J. Org. Chem. 63 (1998) 8163.

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部