期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

利用反向原子转移自由基聚合反应合成聚甲基丙烯酸缩水甘油酯

Synthesis of Poly(glycidyl methacrylate) by Reverse Atom Transfer Radical Polymerization
下载PDF
导出
摘要 以偶氮二异丁腈为引发剂,CuBr2/bpy为催化体系,甲基丙烯酸缩水甘油酯(GMA)通过反向原子转移自由基聚合反应合成了聚甲基丙烯酸缩水甘油酯(PGMA),其结构经1H NMR,IR和GPC确证。聚合反应符合活性自由基聚合特征,在聚合过程中GMA转化率和PGMA分子量随反应时间的延长而增大,分子量分布较窄。 Poly（glycidyl methacrylate）（PGMA） was synthesized by reverse atom transfer radical polymerization of glycidyl methacrylate using CuBr2/bpy as the catalyst system and azodiisobutyronitrile as the initiator.The structure was confirmed by 1H NMR,IR and GPC.Polymerization exhibited the characteristics of living radical polymerization,the molecular weight of PGMA increases and monomer conversion of GMA with the increase of reaction time,and the polydispersity index was narrow.
作者 黄志彬 翁家宝 郑雪琳 王艳芹 孟雪飞
机构地区 福建师范大学化学与材料学院 福建师范大学福建省高分子材料重点实验室
出处 《合成化学》 CAS CSCD 北大核心 2012年第1期94-97,共4页 Chinese Journal of Synthetic Chemistry
基金 国家自然科学基金资助项目(51103025) 福建省教育厅资助项目(JA09049)
关键词 甲基丙烯酸缩水甘油酯 反向原子转移自由基聚合 活性自由基聚合 合成 glycidyl methacrylate reverse atom transfer radical polymerization living radical polymerization synthesis
分类号 O632.51 [理学—高分子化学]
  • 相关文献

参考文献12

  • 1Kamigaito M, Ando T, Sawamoto M. Metal-catalyzed living radical polymerization[J]. Chem Rev,2001,101 (12) :3689 - 3746.
  • 2Matyjaszewski K, Xia J. Atom transfer radical polymerization [ J ]. Chem Rev, 2001,101 ( 9 ) : 2921 - 2990.
  • 3Wang J S, Matyjaszewski K. Controlled/" living" rad- ical polymerization. Atom transfer radical polymerization in the presence of transition-metal complexes[J]. J Am Chem Soc,1995,117(20) :5614 -5615.
  • 4Wang J S, Matyjaszewski K. "Living"/controlled radical polymerization. Transition metal catalyzed atom transfer radical polymerization in the presence of a conventional radical initiator [ J ]. Macromolecules, 1995, 28 (22) : 7572 - 7573.
  • 5Moinean G, Dubois P, Jenome R, et al. Alternative atom transfer radical polymerization for MMA using FeCI3 and AIBN in the presence of triphenylphosphine : An easy way to well-controlled PMMA [ J ]. Macromolecules, 1998,31 (2) :545 - 547.
  • 6Liu B, Hu C P. The reverse atom transfer radical polymerization of methyl methacrylate in the presence of some polar solvents[ J ]. Eur Polym J,2001,37 (10) : 2025 - 2030.
  • 7Zhu S, Yah D, Zhang G. Reverse atom transfer radical polymerization of methyl methacrylate with a new catalytic system, FeCl3/isophthalic acid[ J ]. J Polym Sci,Part A:Polym Chem,2001,39(6) :765 -774.
  • 8Wang W, Griffiths R M T, Naylor A, etal. Preparation of cross-linked microparticles of pely (glycidyl methacrylate) by dispersion polymerization of glycidy] as stabillzer in supercritical carbon dioxide [ J ]. Polymer, 2002, 43 (25) :6653 - 6659.
  • 9May C, ed. Epoxy Resins:Chemistry and Technology [ M ]. Dekker: New York, 1988.
  • 10Xu F J, Chai M Y, Li W B, et al. Well-defined poly [ 2-hydroxyl-3-(2-hydroxyethylamino) propyl methac- rylate ] vectors with low toxicity and high gene transfection efficiency [ J ]. Biomacromolecules, 2010, 11 (6):1437 - 1442.

二级参考文献24

  • 1Norwood R.A.,Blomquist R.Eldada L.et al..Proc.SPIE-Int.Soc.Opt.Eng.[J],1998,3281:2-13
  • 2Robitaille L,Callender C.L.,Noad J.P..Proc.SPIE-Int.Soc.Opt.Eng.[J],1998,3281:14-24
  • 3Dalton L..Adv.Polym.Sci.[J],2002,158:1-86
  • 4Ma Hong,Alex K.Y.Jen.,Dalton L.R..Adv.Mater.[J],2002,14:1339-1365
  • 5Kobayashi J.,Inoue Y.,Matsuura T.et al..IEICE.Trans.Electron[J],1998,E81-C(7):1020-1026
  • 6Ahn J.H.,Lee H.J.,Hwang W.Y.et al..IEICE.Trans.Electron[J],1999,E82-C(2):354-356
  • 7Keil N.,Yao H.J.,Zawadzki C.et al..Electronics Letters[J],2001,37(9):579-580
  • 8Watanable T.,Inoue Y.,Kaneko A.et al..Electronics Letters[J],1997,33(18):1547-1548
  • 9Eunkyoung Kim,Song Yun Cho,Dong-Min Yeu.et al..Chem.Mater.[J],2005,17:962-966
  • 10Kagami M.,Ito H.,Ichikawa T.et al..Appl.Opt.[J],1995,34(6):1041-1046

共引文献5

合成化学
2012年 第1期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部