乳化剂十二烷基硫酸钠(SDS)对淀粉基木材胶特性的影响

Effects of SDS on the Performance of Starch-based Wood Adhesive

研究了乳化剂十二烷基硫酸钠(SDS)对淀粉胶胶接强度和低温储藏稳定性的影响。对比没有加入SDS的淀粉胶,加入SDS后胶的粘结强度均有所提高,最佳添加量为淀粉用量的1%,此时干强度提高了60.1%,湿强度提高了211.5%。此外,SDS可以有效地提高反应的接枝参数,接枝率提高了93.7%,接枝百分率提高了83.8%。耐低温稳定性实验证明,加入乳化剂可以增加淀粉胶通过冷藏-解冻循环的次数。动态时间扫描实验和TEM的结果证明,加入SDS有利于削弱淀粉分子之间的氢键作用力,促进淀粉与单体之间发生接枝反应,从而改善了淀粉胶乳液的粘结性能及稳定性。

The effects of emulsifiers（SDS） on storage stability in low temperature and bond strength of starch-based wood adhesive were investigated.Compared to starch-based wood adhesive without emulsifiers,emulsifier-fortified starch-based wood adhesive all exhibited enhanced glue strength.The optimum amount of SDS is 1% of starch content.In particular,SDS has the most significant effect that dry strength of starch-based wood adhesive was increased by 60.1% and the wet strength was increased by 211.5%,respectively.The grafted parameters were also remarkably increased by adding SDS,for instance G increased by 93.7% and GE increased by 83.8%.It was proved by the stability test of low temperature resistance that emulsifiers can increase the numbers of cooling-thawing circulation.Starch-based wood adhesive with SDS has the best effect from five circulations.The results of dynamic time sweep experiments and TEM showed that SDS could weaken hydrogen＇s bonding strength of the starch molecules,and significantly enhance the parameters of grafted reaction,thereby finally improve the bonding properties and stability of starch-based wood adhesive emulsion.