超分子化合物CdBr_4(DPT)的合成与结构表征

Synthesis and Structure Characterization of Supramolecular Compound CdBr_4(DPT)

用正溴丁烷和4,4'-联吡啶合成了新型的有机阳离子──1,1'-二丁基-4,4'-联吡啶(DPT.Br2),有机阳离子DPT.Br2又与金属盐CdBr2组装成了结构新颖的单核超分子化合物CdBr4(DPT)。通过红外光谱、荧光光谱、X-衍射仪等,表征了CdBr4(DPT)的光谱特征,并解出了其晶体结构。

The novel cation DPT · Br2 has been synthesized by N-butyl bromide and 4,4 J -hipyridine, which is to prepare the novel structured solo supramolecular compound CdBr（DPT） with metal salt CdBr2. Finally, spectrums of CdBr2（DPT） have been characterized, and the crystal structures of CdB4（DPT） have been determined by the means of IR, fluorescence spectrum, and X-ray, etc.