期刊文献+

对苯二酚-果糖树脂的合成与表征

Synthesis and characterization of fructose-hydroquinone resins
下载PDF
导出
摘要 在碱性条件下,使用果糖代替甲醛与对苯二酚反应,成功地制备出环境友好型的对苯二酚-果糖树脂。利用红外、GPC、TGA等对所合成的树脂进行了表征。同时使用响应面优化法优化了反应条件,最优反应条件为:催化剂用量3.99%、反应温度69.97℃、反应时间9.03h、n果糖:n对苯二酚=9.29:1。最优条件时的黏度为222.808mPa?s,拉伸强度15.71~23.61MPa。 The environment-friendly fructose-hydroquinone resins weresynthezised by reaction of fructose instead of formaldehyde with hydroquinone in alkali condition.The fructose-hydroquinone resin was characterized by the infrared spectrum,TG analysis and GPC.Response surface methodology (RSM) was utilized for optimizing the reaction conditions. The results showed that,when the amount of catalyst was 3.99 wt%,reaction temperature was 69.97%,reaction time was 9.03h and molar ratio of fructose and hydroquinone was 9.29,the optimal viscosity of the resultant product was 222.808 mPas and the bonding strength reached 23.6MPa.The fructose-hydroquinone resins are biodegradable,which have better performance in industrial application.
出处 《粘接》 CAS 2012年第2期61-66,共6页 Adhesion
基金 陕西省工业科技攻关项目200K06-G71
关键词 果糖 对苯二酚 响应面 环境友好型 fructose response surface methodology GPC environnlent-friendly
  • 相关文献

参考文献8

二级参考文献19

  • 1胡炬亮,龚颖峰,王禹胜.甲醛捕捉剂在胶合板生产中的应用[J].木材工业,2005,19(1):35-36. 被引量:10
  • 2陈栓虎,刘震,胥学旺.乳糖-间苯二酚树脂胶粘剂的合成[J].中国胶粘剂,2006,15(10):25-27. 被引量:15
  • 3陈栓虎,张蕾,胥学旺.葡萄糖缩二脲树脂胶黏剂的合成[J].化学与粘合,2007,29(1):10-12. 被引量:11
  • 4James Dumesic.Sugary recipe boosts grow-your-own plastics [J]. Science ,2006,312 (30) : 1933.
  • 5Viswanathan, Tito, Gilton T. Improved internal bond strength of high-density particle boards containipg formaldehyde-free whey-based resins on addition for phathalie anhydride[J]. Ind Eng Chem Prod Res Dev, 1986,25(2)z313-315.
  • 6James Dumesic. Sugary recipe boosts grow-your-own plastics [J]. Science, 2006, 312(30): 1933.
  • 7黄发荣,焦扬声.酚醛树脂及其应用[M].北京:化学工业出版社,2004.
  • 8VISWANATHANTITO, RICHARDSONTHOMAS. Thermosetting adhesive resins:US, 4524164[ P]. 1985 -06 - 18.
  • 9VISWANATHANTITO, RICHARDSONTHOMAS. Thermosetting adhesive resins from whey and whey by product [J]. Ind. Eng. Chem. Prod . Res. Dev. , 1984, 23(4) :644 -647.
  • 10JAMES DUMESIC. Sugary recipe boosts grow - your - own plastics [J]. Science, 2006, 312(30) : 1933.

共引文献19

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部