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典型分解炉中硅烷分解沉积速率的研究 被引量:3

Deposition Rate of Polycrystalline Silicon from Monosilane Phyrolysis
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摘要 研究在典型硅烷分解炉中硅烷分解沉积多晶硅的沉积速率。硅烷分解沉积多晶硅实验在硅棒表面温度790~900℃、炉内气压5×104 Pa条件下,探讨硅棒温度、硅烷流速与沉积速率的关系。结果显示:沉积反应活化能53.4kJ/mol。并与真空条件下沉积硅的过程进行对比,提出在典型硅烷分解炉中提高多晶硅沉积速率的可能途径。 This paper studies the deposition rate of monosilane pyrolysis. Experiment is performed in a typical chemica| vapor deposition reactor in a temperature range of 790-900℃ and the pressure of 5×10^4 Pa. It is examined on relationship of silicon rod temperature and gas flow rate to deposition rate during the decomposition process. The activation energy of deposition is estimated to be 53. 4kJ/mol. Compared with reported results on deposition in vacuum reactor, there are some possibilities to increase the deposition rate in a typical chemical vapor deposition reactor.
出处 《浙江理工大学学报(自然科学版)》 2012年第2期263-265,共3页 Journal of Zhejiang Sci-Tech University(Natural Sciences)
关键词 硅烷 多晶硅 沉积速率 silane polycrystalline silicom deposition rate
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  • 1Odden J O, Egeberg P K, Kjekshus A. From monosilane to crystalline silicon part 1: decomposition of monosilane at 690-830 K and initial pressure 0. 1-6.6 MPa in a free space reactor[J]. Solar Energy Material Solar Cells, 2005, 86: 165-176.
  • 2Joyce B A, Bradley R R. Epitaxial growth of silicon from the pyrolysis of monosilane on silicon substrates [J]. Journal of the Electrochemical Society, 1963, 110 (12) : 1235-1240.
  • 3Farrow R F C. The kinetics of silicon deposition on silicon by pyrolysis of silane[J]. Journal of the Electrochemical Society, 1974, 121(7): 899-907.
  • 4Kojima T, Kinetic study of monosilane pyrolysis for polycrystalline silicon production in a fluidized bed [J]. Journal of Chemical Engineering of Japan, 1989, 22(6) : 677-683.

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