环己烷氧化微孔催化剂的研究进展

Development of Microporous Catalysts for Cyclohexane Oxidation

环己烷氧化是化工生产中的重要反应之一,其氧化产物为重要的化工生产中间体,因此开发高效的环己烷氧化多相催化剂体系具有重要的理论意义和应用前景。本文综述了国内外环己烷选择氧化微孔催化剂的研究进展,分别对Y沸石、ZSM-5沸石及MOFs三大类微孔催化剂体系的组成及催化性能进行了介绍,最后展望了环己烷多相催化体系的发展趋势。

The development of highly efficient heterogeneous catalysts for selective oxidation of cyclohexane is of great importance academically and industrially, because important intermediates can be obtained from such oxidation. In this review, zeolite Y, ZSM-5 and MOFs based microporous catalysts for cyclohexane oxidation were introduced with special emphasis on their composition and catalytic performances. Finally, prospects of heterogeneous catalysts for selective oxidation of cyclohexane was described.