摘要
基于新型含能材料1,1-二氨基-2,2-二硝基乙烯(FOX-7)特殊的"推-拉"硝基烯胺结构,总结了FOX-7所能发生的化学反应,包括酸碱反应、配位反应、亲核取代、酰基化反应、氧化反应、还原反应、水解反应、氨基的亲电加成反应、叠氮反应等,从而分析了碳碳双键、氨基部分及硝基部分的反应性能,并讨论了相应的反应路线和反应机理。
Based on the special “push-pull” nitro-enmaine of the novel energetic material I ,1-diamino-2,2-dinitroethene（ FOX-7）, the reported chemical reactions of FOX-7 were summarized, including acid-base reaction, coordination reaction, nucleophilip substitution reaction of amino group,acyl reaction ,oxidation reaction, reduction reaction, hydrolysis reaction, electrophilic addition reaction and azidine reaction. Reactivity of C-C double bond,amino group and nitro group of FOX-7 was analyzed,and reaction routes and mechanisms were also discussed.
出处
《含能材料》
EI
CAS
CSCD
北大核心
2012年第1期120-125,共6页
Chinese Journal of Energetic Materials
基金
国家自然科学基金(20803058)
陕西省教育厅科技专项基金(2010JK881)
火炸药国防重点实验室基金(9140C3503010905)资助
