摘要
由β-蒎烯与多聚甲醛反应制得了诺卜醇,再经Ni(R)催化氢化合成了氢化诺卜醇(ROH)。然后由氢化诺卜醇与亚硫酰氯反应合成了氢化诺卜醇的氯代物(RCl),由氢化诺卜醇与溴化钠和硫酸反应合成了溴代物(RBr),由RCl与碘化钠反应合成了碘代物(RI),各产物的得率均在93%以上,GC含量97%以上。各化合物都进行了IR,1H NMR,13C NMR与MS分析,表征了其结构。
Abstract： Hydronopol was prepared by the hydrogenation of nopol, which was synthesized from/3-pinene and paraformaldehyde in the presence of Raney Ni. Hydronopyl chloride and hydronopyl bromide were synthesized from hydronopol with thionyl chlo- ride, sodium bromide and sulfuric acid, respectively. Hydronopyl iodide was synthesized from hydronopyl chloride and sodium iodide. Identification and structural analysis were done using IR, IH NMR, J3C NMR and MS methods
出处
《林产化学与工业》
EI
CAS
CSCD
北大核心
2012年第1期39-42,共4页
Chemistry and Industry of Forest Products
基金
国家自然科学基金项目(31060101)
教育部留学回国人员科研启动基金项目([2010]1561)
江西省青年科学家(井冈之星)培养对象计划资助项目(无编号)
