摘要
用超声法快速合成了配合物[Zn(H2cit)(H2O)]n(cit为柠檬酸缩写)。所得产物经XRD、FT-IR、FE-SEM和TG-DTA表征,证实其为二维片层结构的微米级金属有机骨架配位聚合物(MOF),其形貌为菱形多面体。并用荧光光谱测定了其发光性能。
Metal-organic framework [Zn(H2cit)(H2O)]n(Citrate abbreviated as cit) was synthesized quickly by ultrasonic method.The as-prepared product was characterized by XRD,FT-IR,FE-SEM and TG-DTA and was confirmed as metal-organic framework with two-dimensional plate-like structure.The morphology of the product was micro-diamond polyhedron.The luminescence of the product was examined by photoluminescence(PL).
出处
《化学工程师》
CAS
2012年第2期13-15,共3页
Chemical Engineer
基金
哈尔滨师范大学科技发展预研项目(10XYG-08)
关键词
金属有机骨架
微米
发光性
metal-organic framework,micron scale; photoluminescence