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Synthesis, Characterization and Ion Exchange Properties of a New Composite of Inorganic Ion Exchanger: Polyacrylonitrile Cerium(IV) Molybdophosphate

Synthesis, Characterization and Ion Exchange Properties of a New Composite of Inorganic Ion Exchanger: Polyacrylonitrile Cerium(IV) Molybdophosphate
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摘要 In this work, the synthesis of the composite of cerium(IV) molybdophosphate (CMP) and polyacrylonitrile (PAN) was reported (CMP-PAN). The material has been characterized by elemental and spectral (FT-IR), X-ray and thermal (TGA) analysis. Also the size analysis of the composite was done by scanning electron microscopy (SEM). Its chemical stability in acidic, basic and saline solutions and radiation stability up to 100 kGy total expose dose were assessed. Whereas the synthesized composite has ion exchange properties, its ion exchange capacity and behavior toward several metal ions were also investigated. Further, the distribution coefficients of the metal ions were calculated. Finally, the ability of the synthesized CMP-PAN composite for the decontamination of low level liquid waste (LLLW) was investigated. In this work, the synthesis of the composite of cerium(IV) molybdophosphate (CMP) and polyacrylonitrile (PAN) was reported (CMP-PAN). The material has been characterized by elemental and spectral (FT-IR), X-ray and thermal (TGA) analysis. Also the size analysis of the composite was done by scanning electron microscopy (SEM). Its chemical stability in acidic, basic and saline solutions and radiation stability up to 100 kGy total expose dose were assessed. Whereas the synthesized composite has ion exchange properties, its ion exchange capacity and behavior toward several metal ions were also investigated. Further, the distribution coefficients of the metal ions were calculated. Finally, the ability of the synthesized CMP-PAN composite for the decontamination of low level liquid waste (LLLW) was investigated.
出处 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2012年第1期177-182,共6页 中国化学(英文版)
关键词 COMPOSITE ion-exchange cerium(IV) molybdophosphate composite, ion-exchange, cerium(IV) molybdophosphate
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