摘要
A series of chiral two-dimensional lanthanide coordination polymers, [Ln2(L)3(H2O)6]n·n/3H2O[Ln=Nd (la, lb), Sm (2), Eu (3), Tb (4), Dy (5), Ho (6), Er (7); H2L=2,2-dihydroxylmalonic acid], have been hydrothermally synthesized by using dihydroxyfumaric acid as a source of polydentate O-donor ligands. The luminescence behav- iors of 3 and 4 have been investigated, and they exhibit strong red and green fluorescence in the visible region respectively.
A series of chiral two-dimensional lanthanide coordination polymers, [Ln2(L)3(H2O)6]n·n/3H2O[Ln=Nd (la, lb), Sm (2), Eu (3), Tb (4), Dy (5), Ho (6), Er (7); H2L=2,2-dihydroxylmalonic acid], have been hydrothermally synthesized by using dihydroxyfumaric acid as a source of polydentate O-donor ligands. The luminescence behav- iors of 3 and 4 have been investigated, and they exhibit strong red and green fluorescence in the visible region respectively.
基金
This work was financially supported by the National Natural Science Foundation of China (No. 20871046), the Program for Excellent Talents in Hunan Normal University (No. 090619), the Scientific Research Fund of Hunan Provincial Education Department (No. 11B077), and the Aid Program for Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province.