原子簇化合物的固相合成及其三阶非线性光学性质的研究

Studies on the Solid State Synthesis and the Third Order Nonlinear Optical Properties of the Mo(W)/S/Cu(Ag) Cluster Compounds

在戴安邦教授的指导下 ,我们实验室多年来在室温、近室温条件下采用固相反应法合成了一系列原子簇化合物 ,本文则对用此方法合成的Mo(W ) /S/Cu(Ag)原子簇化合物进行了分类和总结 ,并探讨了固相反应合成原子簇化合物的成簇规律和成簇机理。同时本文还概括和总结了Mo(W ) /S/Cu(Ag)原子簇化合物的光限制效应 ,三阶非线性吸收与非线性折射等光学性质 ,初步探讨了Mo(W ) /S/Cu(Ag)

Under the guidance of professor DAI An Bang, We use solid state reaction to synthesize a series of Mo(W)/S/Cu(Ag) cluster compound in room and near room temperature. In this paper, the Mo(W)/S/Cu(Ag) cluster compounds synthesized through this method are classified and summarized. The regularity and the possible mechanism of the cluster formation are discussed. This paper also summarizes the optical limiting effects, the third order nonlinear absorption and refraction of Mo(W)/S/Cu(Ag) cluster compounds. The correlation between nonlinear optical properties and structural types is also discussed preliminarily.