期刊文献+

受阻酚抗氧剂对NBR/WCB共混胶耐热老化性能的影响 被引量:3

Effect of hindered phenolic antioxidants on thermal aging properties of NBR/WCB blends
下载PDF
导出
摘要 研究了抗氧剂2-叔丁基-6-(3-特丁基-2-羟基-5-甲基苯基)-4-甲基苯酚丙烯酸酯(简称GM)、抗氧剂264和抗氧剂2246对NBR/WCB共混胶的硫化特性、力学性能和耐热老化性能的影响,并通过TG分析表征NBR/WCB共混胶的耐热稳定性。结果表明,与抗氧剂264和抗氧剂2246相比,抗氧剂GM对NBR/WCB共混胶具有防止焦烧、加快硫化速度和软化胶料的作用。添加抗氧剂GM的共混胶比加入抗氧剂264和2246的共混胶具有更优异的耐热老化性能。TG分析表明,在3种抗氧剂中,加入抗氧剂GM的NBR/WCB共混胶的耐热稳定性最高。 The effect of hindered phenolic antioxidants such as GM,264 and 2246 on curing characteristics,mechanical properties and thermal aging properties of NBR/WCB blends had been investigated and thermal stability of NBR/WCB blends was characterized by TG analysis.The results showed that antioxidant GM has an effect of anti-scorching,fastening curing speed and softening elastomer on NBR/WCB blends.The NBR/WCB blends added with antioxidant GM exhibits better thermal aging properties than those with antioxidant 264 and 2246.TG analysis showed that the thermal stability of the blends with the addition of antioxidant GM is better than that with antioxidant 264 and 2246.
出处 《弹性体》 CAS 2012年第1期50-54,共5页 China Elastomerics
基金 2009年省部产学研结合项目 华南理工大学中央高校基本科研业务费项目(2011ZM0128)
关键词 受阻酚抗氧剂 丁腈橡胶 GM 耐热老化性能 TG hindered phenolic antioxidant NBR GM thermal aging property TG analysis
  • 相关文献

参考文献10

  • 1王克智.新型耐热双酚单丙烯酸酯类抗氧剂[J].现代塑料加工应用,1992,4(6):30-33. 被引量:8
  • 2Jan P.Chemical and photochemical behaviour of phenolicantioxidants in polymer stabilization-a state of the art re-port,Part I[J].Polymer Degradation and Stability,1993,40(2):217-232.
  • 3王克智,李好样.双酚单丙烯酸酯热稳定剂[J].合成橡胶工业,1995,18(1):47-49. 被引量:8
  • 4王克智,李训刚.聚合物稳定化助剂技术进展[J].中国塑料,2001,15(4):1-6. 被引量:38
  • 5杜飞.双酚单丙烯酸酯类抗氧剂GM的合成[J].精细化工,2006,23(10):1007-1010. 被引量:12
  • 6Shinichi Y,Manji S,Yukoh T,et al.Studies on polymer sta-bilizers:Part I-A novel thermal stabilizer for butadiene poly-mers[J].Polymer Degradation and Stability,1988,22(1):63-77.
  • 7Shinichi Y,Manji S,Kanako T,et al.Studies on polymerstabilizers:Part VI-Relationship between performance andmolecular conformation[J].Polymer Degradation and Sta-bility,1993,39(3):329-343.
  • 8韦春,孙海波,戴培邦,高群学.GM橡胶防老剂的研究[J].桂林工学院学报,2000,20(3):256-259. 被引量:11
  • 9Muse,Joel G,Donald C.Gel prevention in polymers[P].USP:US4847313,1989-07-11.
  • 10Gan L,Ye L.The thermal stabilization effect of biphenolmonoacrylate on polyoxymethylene[J].Journal of Thermo-plastic Composite Materials,2010,23(4):543-559.

二级参考文献19

  • 1张萍,赵树高,武玉斌,张玉成.复合型防老剂8PPD在橡胶中的应用[J].橡胶工业,1995,42(1):8-13. 被引量:6
  • 2刘毓真,张贵新,刘海宇.防老剂WH-02对NR胶料热氧老化的防护[J].橡胶工业,1996,43(3):131-134. 被引量:4
  • 3陈经盛,郑云中.橡胶大气老化应力松弛的评价[J].橡胶工业,1997,44(2):67-71. 被引量:4
  • 4Al Malaikas,Polym Degrad Stab,1999年,65卷,143页
  • 5Gugumu S F,Polym Degrad Stab,1999年,66期,133页
  • 6王克智,精细与专用化学品,1999年,15期,15页
  • 7王克智,中国塑料,1998年,12卷,3期,20页
  • 8Takat Takesh, Yachigo Shinichi, Sasaki Manji,et al. Butadiene polymer composition containing phenolic compound and phosphorus-containing compound[P]. US :5 045 581,1988.
  • 9木村键治.ボリブタジェン组成物[P].JP:2000143873,2000.
  • 10Shin'ichi Yachigo, et al. Studies on polymer stsbilizers:Part V-Influences of structural factors on oxidative discoloration and thermal stability of polymers [J]. Polymer Degradation and Stability, 1993, ( 39 ) :317 - 328.

共引文献56

同被引文献29

引证文献3

二级引证文献13

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部