2,2,2-三氟乙腈的制备与应用前景展望
Application and Synthesis of Trifluoroacetonitrile
摘要
三氟乙腈是一种重要的亲电试剂,是一个很好的合成子,广泛用于农药及医药产品的合成。本文详细介绍了三氟乙腈的合成方法以及其应用情况。
Trifluoroacetonitrile is an important electrophilic agent.It is a good synthon and is widely used in the synthesis of pharmaceuticals and insecticides.In this paper,the synthesis of trifluoroacetonitrile and its application was reviewed.
出处
《浙江化工》
CAS
2012年第2期1-3,24,共4页
Zhejiang Chemical Industry
关键词
三氟乙腈
合成
应用
三氟乙酰胺
三氟乙酸
Trifluorocaetonitrile
synthesis
application
trifluoroacetamide
,trifluoroacetic acid
参考文献13
-
1Robert P Ruh,Ralph A Davis.Fluorination ofperhaloacetonitriles over an improced chromium fluoridecatalyse:US,2745867[P].1956-05-15.
-
2Robert P Ruh,Ralph A Davis.Preparation offluoronitriles:US,2939878[P].1960-06-07.
-
3Takamatsu Shiyuuichi,Misaki Susumu.Preparation offluoronitriles:JP,59118751[P].1984-07-09.
-
4Kenkyu Hokoku-Asahi Garasu Kogyo GijutsuShoreikai,1975,27:1-10.
-
5Minnesota Mining.Electrolysis of metal fluorides inthe presence of a pseudo-halogen:US,3032488[P].1962-05-01.
-
6Franciszek olstowski.Preparation of fluorocarbonnitriles:US,3017336[P].1962-01-16.
-
7Campagna F,Cartti A,Carsini G.A convenientsynthesis of nitriles from primary amides under mild conditions[J].Tetrahedron letters,1977,(21):1813-1816.
-
8Marshall H Parker.A Conveniert preparation oftrifluoroacetonitrile application to the synthesis of a novelpyrimidinone builiding block[J].Synthesis Communications,2004,34(5):903-907.
-
9Eisaku Yamato,Shigehiko Sugasawa.Preparation ofnitrile from primary amide[J].Tetrahedron letters,1970,50:4383-4384.
-
10Engelbert Ciganek.Iminophosphoranes from thereaction of ylide with nitriles[J].J.Org.Chem.,1970,35:3631-3636.
-
1范小娜,黄玲,黄志勤,李青松,丁冶春,程庚金生.三种羟基羧酸气相色谱法的分离及定量分析[J].江西师范大学学报（自然科学版）,2004,28(6):537-539. 被引量：4
-
2葛少林,佘世科,徐迎波,黄兰,张朝,刘非.烟草中挥发性与半挥发性有机酸的GC-MS法快速检测[J].香料香精化妆品,2014(2):31-40. 被引量：5
-
3金晓峰,章厉劼,古海.气相色谱-质谱联用法测定饲料中盐酸克仑特罗的分析[J].饲料工业,2007,28(10):51-53.
