摘要
Slag corrosion resistance of MgO -ZrO2 refractories was inrestigated ill this work. The resuhs indicate that in a non-oriented electric steel slag systenl with a high ratio of ealci^t to silica, the slag resistance of MgO - ZrO, refractories can be described as flllows : ZrO2 reacts with GtO .forming calcium zireonate compound which strengthens the material and blocks the channel of the slag infihration ; however, in an oriented electric steel slag system with a high concentration of silica and the low ratio of calcia to silica, the slag corrosion resistance ofM gO-ZrO: refractories is different ; ZrO2 reaets with CaO forming the ealcium zirconate and simultaneously one more product C2S as well; C2S cam improve corro- sion resistance by blinding pore and enhancing slag viscosity; therefore, it is expected to be the major reason for the enham'ed corrosion resistance observed for MgO-ZrO2 refractories.
Slag corrosion resistance of MgO -ZrO2 refractories was inrestigated ill this work. The resuhs indicate that in a non-oriented electric steel slag systenl with a high ratio of ealci^t to silica, the slag resistance of MgO - ZrO, refractories can be described as flllows : ZrO2 reacts with GtO .forming calcium zireonate compound which strengthens the material and blocks the channel of the slag infihration ; however, in an oriented electric steel slag system with a high concentration of silica and the low ratio of calcia to silica, the slag corrosion resistance ofM gO-ZrO: refractories is different ; ZrO2 reaets with CaO forming the ealcium zirconate and simultaneously one more product C2S as well; C2S cam improve corro- sion resistance by blinding pore and enhancing slag viscosity; therefore, it is expected to be the major reason for the enham'ed corrosion resistance observed for MgO-ZrO2 refractories.
作者
YUAN Lin1,CHEN Songlin1,2,ZENG Luju1,LIU Xijun1,WU Xingsheng1,SUN Jialin2 1 Ruitai Materials Technology Co. Ltd. ,China Building Materials Academy,Beijing 100024,China 2 School of Materials Science and Engineering,University of Science and Technology Beijing, Beijing 100083,China