期刊文献+

锂离子电池正极材料磷酸锰锂的研究进展 被引量:5

Research progress in Li-ion battery cathode material lithium manganese phosphate
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摘要 对固相法、水热法、溶胶-凝胶法、多羟基化法、沉淀法、喷雾干燥法和模板法等合成正极材料LiMnPO4进行了综述,分析了这些方法的优缺点;总结了为改善材料电化学性能进行的碳包覆或掺杂工作;在LiMnPO4热稳定性方面还存在不同的认识,对热稳定性方面的相关研究做了总结。 The synthesis procedures, such as solid-state method, hydrothermal method, solgel method, polyol method, precipitation method, spray dry method and template assisted method, for production of cathode material lithium manganese phosphate (LiMnPO4) were summarized. The advantages and disadvantages of these methods were analyzed. The carbon coating and doping for improving the electrochemical performance of the material was summarized. There were still some doubts in the thermal stability of LiMnPO4, the related research was also reviewed.
出处 《电池》 CAS CSCD 北大核心 2012年第1期39-42,共4页 Battery Bimonthly
关键词 正极材料 合成 改性 稳定性 磷酸锰锂(LiMnPO4) cathode material synthesis modification stability lithium manganese phosphate(LiMnPO4)
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参考文献34

  • 1Arcon D,Zorko A,Dominko R,et al.A comparative study ofmag-netic properties of LiFePO4 and LiMnPO4[J].J Phys:CondensMatter,2004,16(30):5 531-5 548.
  • 2Wizent N,Behr G,Lipps F,et al.Single-crystal growth of LiMn-PO4by the floating-zone method[J].J Cryst Growth,2009,311(5):1 273-1 277.
  • 3Delacourt C,Laffont L,Bouchet R,et al.Toward understanding ofelectrical limitations(electronic,ionic)in LiMPO4(M=Fe,Mn)electrode materials[J].J Electrochem Soc,2005,152(5):A913-A921.
  • 4Yamada A,Hosoya M,Chung S C,et al.Olivine-type cathodesachievements and problems[J].J Power Sources,2003,119(1):232-238.
  • 5王国宝,王先友,舒洪波,王英平.LiFePO_4/C复合材料的固相合成及碳源的影响[J].电池,2009,39(6):340-342. 被引量:11
  • 6Li G H,Azuma H,Tohda M.LiMnPO4 as the cathode for lithiumbatteries[J].Electrochem Solid-State Lett,2002,5(6):A135-A137.
  • 7Chen J,Wang S,Whittingham M S.Hydrothermal synthesis ofcathode materials[J].J Power Sources,2007,174(2):442-448.
  • 8Chen J,Vacchio M J,Wang S J,et al.The hydrothermal synthesisand characterization of olivines and related compounds for electro-chemical applications[J].Solid State Ionics,2008,178(31-32):1 676-1 693.
  • 9Fang H S,Li L P,Yang Y,et al.Carbonate anions controlled mor-phological evolution of LiMnPO4 crystals[J].Chem Commun,2008,(9):1 118-1 120.
  • 10Wang Y R,Yang Y F,Yang Y B,et al.Enhanced electrochem-ical performance of unique morphological LiMnPO4/C cathodematerial prepared by solvothermal method[J].Solid State Com-mun,2010,150(1-2):81-85.

二级参考文献50

  • 1王志高,李建玲,王新东.LiFePO_4/C的微波法制备和性能[J].电池,2006,36(2):142-143. 被引量:6
  • 2魏琦峰,李宁,任秀莲,韩家军,张天云,杜杰.正极材料LiFePO_4的研究现状[J].电池,2006,36(3):240-242. 被引量:3
  • 3张自禄,卢嘉春,李雪松,杨裕生.LiFePO_4的蔗糖改性研究[J].电池,2007,37(1):3-5. 被引量:10
  • 4Chung S Y, Bloking J T, Chiang Y M. Electronically conductive phospho-olivines as lithium storage electrodes [ J]. Nat Mater, 2002,1 (2) : 123 - 128.
  • 5Mi C H,Cao Y X,Zhang X G, et al. Synthesis and characterization of LiFePO4/( Ag + C) composite cathodes with nano-carbon webs[J]. Power Technology,2008,181 (3) :301 - 306.
  • 6Dong Y Z,Zhao Y M,Chen Y H, et al. Optimized carbon-coated LiFePO4 cathode material for lithium-ion batteries [ J ] . Mater Chem Phys, 2009,115 ( 1 ) : 245 - 250.
  • 7Shin H C,Cho W I,Jang H. Electrochemical properties of the carbon-coated LiFePO4 as a cathode material for lithium-ion secondary batteries[J]. J Power Sources,2006,159(2) : 1 383 - 1 388.
  • 8Kim J K, Cheruvally G, Ahn J H. Electrochemical properties of LiFePO4/C synthesized by mechanical activation using sucrose as carbon source[J]. J Solid State Electrochem,2008,12(7 - 8) :799 - 805.
  • 9Padhi, A. K.; Najundaswamy, K. S.; Goodenough, J. B.J. Electrochem. Soc., 1997, 144:1188
  • 10Padhi, A. K.; Najundaswamy, K. S.; Masquelier, C.; Okada, S.;Goodenough, J. B. J. Electrochem. Soc., 1997, 144:1609

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