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10BaF_2:NaF,Na_3AlF_6/TiO_2 composite as a novel visible-light-driven photocatalyst based on upconversion emission 被引量:1

10BaF_2:NaF,Na_3AlF_6/TiO_2 composite as a novel visible-light-driven photocatalyst based on upconversion emission
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摘要 A rare-earth free upconversion luminescent material, 10BaF2:NaF, Na3AIF6, is synthesized by a hydrothermal method. The study of fluorescent spectrum indicates that it can convert visible light (550 nm-610 nm) into ultraviolet light (290 nm 350 nm), and two emission peaks at 304 nm and 324 nm are observed under the excitation of 583 nm at room temperature. Subsequently, 10BaF2:NaF, Na3AIF6/TiO2 composite photocatalyst is prepared and its catalytic activity is evaluated by the photocatalytic reduction of CO2 under visible light irradiation (λ〉 515 nm). The results show that 10BaF2:NaF, Na3AIF6/TiO2 is a more effective photocatalyst for CO2 reduction than pure TiO2, their corresponding methanol yields are 179 and 0 μmol/g-cat under the same conditions. Additionally, the mechanism of photocatalytic reduction of CO2 on 10BaF2:NaF, Na3AIF6/TiO2 is proposed. A rare-earth free upconversion luminescent material, 10BaF2:NaF, Na3AIF6, is synthesized by a hydrothermal method. The study of fluorescent spectrum indicates that it can convert visible light (550 nm-610 nm) into ultraviolet light (290 nm 350 nm), and two emission peaks at 304 nm and 324 nm are observed under the excitation of 583 nm at room temperature. Subsequently, 10BaF2:NaF, Na3AIF6/TiO2 composite photocatalyst is prepared and its catalytic activity is evaluated by the photocatalytic reduction of CO2 under visible light irradiation (λ〉 515 nm). The results show that 10BaF2:NaF, Na3AIF6/TiO2 is a more effective photocatalyst for CO2 reduction than pure TiO2, their corresponding methanol yields are 179 and 0 μmol/g-cat under the same conditions. Additionally, the mechanism of photocatalytic reduction of CO2 on 10BaF2:NaF, Na3AIF6/TiO2 is proposed.
出处 《Chinese Physics B》 SCIE EI CAS CSCD 2012年第4期249-256,共8页 中国物理B(英文版)
基金 supported by the National Natural Science Foundation of China (Grant No. 20876125) the Research Fund for the Doctoral Program of Higher Education, China (Grant No. 20096101110013) the Northwest University Graduate Interdisciplinary Funds, China (Grant Nos. 09YJC24 and 09YJC27)
关键词 rare-earth free upconversion luminescent material ultraviolet emission titanium dioxide photocatalytic reduction of CO2 rare-earth free upconversion luminescent material, ultraviolet emission, titanium dioxide, photocatalytic reduction of CO2
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