期刊文献+

CaTiO_3:Zn纳米粉体的溶胶凝胶法制备及性能研究

Preparation and properties of CaTiO_3:Zn nanoparticles based on sol-gel method
下载PDF
导出
摘要 采用溶胶凝胶法制备了CaTiO3∶Zn纳米粉体,研究了所制粉体的微观结构及性能。结果表明,所制粉体粒径约50 nm,主晶相为CaTiO3,Zn以Zn2TiO4形式存在于晶相中。1 150℃下烧结所得CaTiO3∶Zn纳米粉体性能较优:比固相法的烧结温度降低约250℃,相对介电常数εr=155,品质因数Q.f提高至6 633 GHz。 Nano-sized CaTiO3;Zn particles were successfully synthesized through sol-gel technique. The microstructure and other properties of the prepared nano particles were investigated. The average particle size of the CaTiO3 : Zn powders calculated from TEM micrograph is about 50 nm. CaTiO3 is formed as the 'major phase, and the added Zn exists as Zn2TiO4 phase. The CaTiO3 : Zn ceramics can be well sintered at 1 150℃, about 250 ℃ lower than those of ceramics obtained by conventional solid state method. The sintered CaTiO3: Zn ceramics possess a gr of 155, and a Q· fvalue of 6 633 GHz which is greatly improved.
出处 《电子元件与材料》 CAS CSCD 北大核心 2012年第4期7-9,共3页 Electronic Components And Materials
基金 国家科技支撑计划资助项目(No.2009BAG12A07) 浙江省创新团队项目资助(No.2011R09010)
关键词 CaTiO3∶Zn 溶胶凝胶法 纳米粒子 介电性能 CaTiO3:Zn sol-gel technique nanoparticles dielectric properties
  • 相关文献

参考文献18

  • 1黄永峰,李谦,黄金亮,龙永强,殷镖.高介电常数微波介质陶瓷的发展及研究现状[J].硅酸盐通报,2006,25(4):115-119. 被引量:8
  • 2王光辉,梁小平,史奕同,陆青.高介电常数微波介质陶瓷材料的研究现状[J].硅酸盐通报,2008,27(2):312-317. 被引量:16
  • 3LI J M,QIU T,FAN C G,et al.Synthesis and microwave dielectricproperties of Ca0.6La0.267TiO3 nanocrystalline powders by sol-gel method[J].J Sol-Gel Sci Technol,2011,59:525-531.
  • 4LEE W H,LEE Y C.Microwave dielectric properties of Mn-dopedBaO-(Nd0.7Sm0.3)2O3-4TiO2ceramic sintered in a reducing atmosphere[J].Ceram Int,2010,36:181-185.
  • 5ZHANG Q L,SUN H P,YANG H.Low-temperature sintering anddielectric properties of high-permittivity microwave(Ca,Nd)TiO3ceramics[J].Alloys Compd,2011,509:9986-9991.
  • 6LIANG B L,ZHENG X H,TANG D P.New high-εand high-Qmicrowave dielectric ceramics:(1 x)Ca0.61Nd0.26TiO3-xNd(Zn0.5Ti0.5)O3[J].J Alloys Compd,2009,488:409-413.
  • 7JACOB K S,SATHEESH R.Preparation and microwave characterizationof BaNd2–xSmxTi4O12(0≤x≤2)ceramics and their effect on thetemperature coefficient of dielectric constant in polytetrafluoroethylenecomposites[J].Mater Res Bull,2009,44:2022-2026.
  • 8杨秋红,金应秀,徐军.固溶率因子R对(Pb,Ca,La)(Fe,Nb)O_3陶瓷微波介电性能的影响[J].硅酸盐学报,2002,30(5):554-558. 被引量:13
  • 9HU M Z,ZHOU D X,GU H S,et al.Influence of Bi2O3and MnO2dopingon microwave properties of(Pb,Ca,La)(Fe,Nb)O3dielectric ceramics[J].Mater Sci Eng B,2005,117(2):199-204.
  • 10HUANG C L,HOU J J,PAN C L,et al.Effect of ZnO additive on sinteringbehavior and microwave dielectric properties of 0.95MgTiO3-0.05CaTiO3ceramics[J].J Alloys Compd,2008,450(1/2)359-363.

二级参考文献49

  • 1黄国华,周东祥,陈晓平,罗慧倩.EDTA络合法合成CSLNT陶瓷粉体[J].华中科技大学学报(自然科学版),2004,32(9):28-30. 被引量:4
  • 2[1]KATO J, KAGATA H, NICHIMOTO K. Dielectric properties of lead alkaline earth zirconate at microwave frequencies [J]. Jpn J Appl Phys, 1991,30:2 343-2 346.
  • 3[2]KATO J, KAGATA H, NICHIMOTO K. Dielectric properties of (PbCa)(MeNb)O3 at microwave frequencies [J]. Jpn J Appl Phys, 1992, 31:3 144-3 147.
  • 4[3]KAGATA H, KATO J, NICHIMOTO K, et al. Dielectric properties of Pb_based perovskites substituted by Ti for B_site at microwave frequencies [J]. Jpn J Appl Phys, 1993, 32:4 332-4 334.
  • 5[4]KUCHEIKO S, CHOI J W, KIM H J, et al. Microwave characteristics of (Pb,Ca)(Fe,Nb,Sn)O3 dielectric materials [J]. J Am Ceram Soc, 1997, 80(11):2 937-2 940.
  • 6[5]KIM I S, JUNG W H, INAGUMA Y, et al. Dielectric properties of A_site deficient perovskite_type lanthanum_calcium_titanium oxide solid solution system [(1-x)La2/3TiO3-xCaTiO3(0.1<x<0.96)] [J].Mater Res Bull, 1995, 30(3):307-316.
  • 7[6]YOSHIDA M, HARA N, TAKADA T, et al. Structure and dielectric properties of (Ca1-xNd2x/3)TiO3 [J]. Jpn J Appl Phys, 1997, 36:6 816-6 823.
  • 8[7]KIM W S, KIM E S, Yoon K H. Effect of Sm3+ substitution on dielectric properties of Ca1-xSm2x/3TiO3 ceramics at microwave frequencies [J]. J Am Ceram Soc, 1999, 82(8):2 111-2 115.
  • 9[8]MICHIURA N, TATEKAWA T, HIGUCHI Y, et al. Role of donor and acceptor ions in the dielectric loss tangent of (Zr0.8*Sn0.2)TiO4 dielectric resonator material [J]. J Am Ceram Soc, 1995,78(3):793-796.
  • 10[9]SHANNON R D. Dielectric polarizabilities of ions in oxides and fluorides [J]. J Appl Phys, 1993, 73(1): 348-366.

共引文献33

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部