Synthesis and Crystal Structure of 2,2'-Dihydroxy-[1,1']binaphthalenyl-3,3'-bis-hydroxamic Acids

Synthesis and Crystal Structure of 2,2'-Dihydroxy-[1,1']binaphthalenyl-3,3'-bis-hydroxamic Acids

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摘要 The first synthesis and structural characterization by X-ray crystallography of racemic 2,2＇-dihydroxy-[1,1＇]binaphthalenyl-3,3＇-bis-hydroxamic acids were reported.The com-pound（C28H30N4O8,Mr = 550.56） crystallizes in orthorhombic system,Fdd2 space group with a = 13.055（3）,b = 34.871（7）,c = 12.570（3） ,V = 5722（2） 3,Z = 8,Dc = 1.278 g/cm3,λ = 0.71073 ,μ（MoKα） = 0.095 mm-1,F（000） = 2320,S = 1.021,R = 0.0349 and wR = 0.0802 for 1757 observed reflections with I 〉 2σ（I）.The N-H and O atom are involved in two-dimensional intermolecular hydrogen bond nets,which further stabilize the structure. The first synthesis and structural characterization by X-ray crystallography of racemic 2,2＇-dihydroxy-[1,1＇]binaphthalenyl-3,3＇-bis-hydroxamic acids were reported.The com-pound（C28H30N4O8,Mr = 550.56） crystallizes in orthorhombic system,Fdd2 space group with a = 13.055（3）,b = 34.871（7）,c = 12.570（3） ,V = 5722（2） 3,Z = 8,Dc = 1.278 g/cm3,λ = 0.71073 ,μ（MoKα） = 0.095 mm-1,F（000） = 2320,S = 1.021,R = 0.0349 and wR = 0.0802 for 1757 observed reflections with I 〉 2σ（I）.The N-H and O atom are involved in two-dimensional intermolecular hydrogen bond nets,which further stabilize the structure.

作者黄婉云陈自卢秦愫妮刘冬成梁福沛

机构地区 State Key Laboratory of Coordination Chemistry State Key Laboratory Cultivation Base for the Chemistry and Molecular Engineering of Medicinal Resources

出处《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2012年第3期438-442,共5页 结构化学（英文）

基金 Supported by the National Natural Science Foundation of China (No. 20971029) Natural Science Foundation of Guangxi Province (No. 2010GXNSFD013018 and 2010GXNSFF013001)

关键词 hydroxamic acid 1-binaphthyl compound crystal structure SYNTHESIS hydroxamic acid 1-binaphthyl compound crystal structure synthesis

分类号 O621.3 [理学—有机化学]

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Chinese Journal of Structural Chemistry

2012年第3期

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Synthesis and Crystal Structure of 2,2'-Dihydroxy-[1,1']binaphthalenyl-3,3'-bis-hydroxamic Acids

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