过渡金属有机化合物的取代反应

Substitution Reaction of Transition Organometallic Compounds

综述了有关金属有机化合物取代反应的机理研究及其配体的电子效应,立体效应以及螯合效应等的因素对取代反应的影响。

This article reviews the substitution reaction of organotransition metal compounds. The reaction mechanism is affected by the electronic density on the metal and its ligands, the stereochemical environment around the metal centre and the chelation effect of its ligands.