摘要
The title compound [CuI(PPh3)(bpy)] was synthesized and the structure was determined by X ray diffraction. The crystal belongs to monoclinic system, and C2/C space group. The cell parameters are a=28.206(5) ?, b=9.447(2) ?, c=19.025(4) ?, β=90.51(3)°, V= 5069(2)?3, Z=8, Dc=1.601 g·cm-3. The Cu atom is in the center of the distorted coordination tetrahedron.
The title compound [CuI(PPh3)(bpy)] was synthesized and the structure was determined by X ray diffraction. The crystal belongs to monoclinic system, and C2/C space group. The cell parameters are a=28.206(5) ?, b=9.447(2) ?, c=19.025(4) ?, β=90.51(3)°, V= 5069(2)?3, Z=8, Dc=1.601 g·cm-3. The Cu atom is in the center of the distorted coordination tetrahedron.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2000年第1期111-114,共4页
Chinese Journal of Inorganic Chemistry
基金
北京市科技新星项目资助!(No.952871800)
关键词
铜(Ⅰ)配合物
晶体结构
三苯基膦
联吡啶
copper(I) complex crystal structure bipyridine triphenylphosphine
