期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

六氟-2-丁烯的合成研究进展 被引量：4

Review on Synthesis of 1,1,1,4,4,4-Hexafluoro-2-Butene
下载PDF
导出
摘要 六氟-2-丁烯(HFC-1336)ODP值为零,GWP值很低(GWP100 yr ITH=9.4(NOAA)),是发泡剂HCFC-141b的理想替代品之一。对其合成方法进行了文献综述,在文献基础上得出以六氟-2,3-二氯-2-丁烯(R1316)为原料经两步反应合成HFC-1336的工艺具有工业化应用前景。 1,1,1,4,4,4 - Hexafluoro - 2 - Butene is a halon alternative. Its properties on ozone depletion po- tential （ ODP = 0 ）, global warming potential （ GWP10o yr ~TH = 9. 4 （NOAA） ） are superior to other halon alterna- tives. This paper is a review on synthesis of 1,1,1,4,4,4 - hexafluoro - 2 - butene, and indicates that the route of R1316 as a raw material may be an industrial strategy.
作者 付庆 孙晓刚 向绍基 孔小林
机构地区 浙江省化工研究院中化蓝天技术研发中心
出处 《有机氟工业》 CAS 2012年第1期30-33,共4页 Organo-Fluorine Industry
关键词 六氟-2-丁烯 六氟-2-丁炔 R1316 加氢反应 脱氯反应 锌粉 合成 1,1,1,4,4,4 - hexafluoro - 2 - butene 1,1,1,4,4,4 - hexafluoro - 2 - butylene R1316 hydro-genation deehlorination zinc power synthesis
分类号 TQ222.4 [化学工程—有机化工]
  • 相关文献

参考文献25

  • 1Helen Walter-Terrinoni.DuPont FEA-1100:Zero ODP,Low GWP,Non-Flammable Alternative for HCFC-141b.
  • 2Kontomaris,Konstantinos.Chiller apparatus containingtrans-1,1,1,4,4,4-hexafluoro-2-butene and meth-ods of producing cooling therein:WO,2011034904[P].2011-03-24.
  • 3Loh Gary,Creazzo,Joseph Anthony.Composition and use oftrans-1,1,1,4,4,4-hexafluoro-2-butene foam form-ing composition in the preparation of polyisocyanate-basedfoams:WO,2009014966[P].2009-01-29.
  • 4Robin,Mark L.Azeotrope-like compositions of(E)-1,1,1,4,4,4-hexafluoro-2-butene and 1-chloro-3,3,3-trifluoropropene:US,20110260093[P].2011-10-27.
  • 5Robin,Mark L,Miller,et al.Azeotropic and azeotrope-like compositions of(E)-1,1,1,4,4,4-hexafluoro-2-butene and ethylene oxide and uses thereof:WO,2011106652[P].2011-09-01.
  • 6Robin,Mark L.Azeotropic and azeotrope-like composi-tions of(E)-1,1,1,4,4,4-hexafluoro-2-butene:WO,2008154612[P].2008-12-18.
  • 7Haszeldine R N.The addition of free radicals to unsaturatedsystems.Part I.The direction of radical addition to 3,3,3-trifluoropropene[J].Journal of the Chemical Society,1952:2504-2513.
  • 8Van der Puy,Michael Ma J J.Process for the preparation ofperfluorinated cis-alkene:WO,2010014548[P].2010-04-01.
  • 9Swearingen,Ekaterina N.High selectivity process to makedihydrofluoroalkenes:WO,2009142642[P].2009-11-26.
  • 10Swearingen,Ekaterina N.High selectivity process to makedihydrofluoroalkenes:US,20080269532[P].2008-10-30.

同被引文献70

  • 1Van D P, Michael ,Ma J J. Process for the preparation of perfluorinated cis - alkene : WO, 2010014548 [ P ]. 2010 - 02 -04.
  • 2Swearingen E N. High selectivity process to make dihydroflu- oro&lkenes by hydrogenation of fluorinated alkynes: WO, 2009142642 [ P]. 2009 - 11 - 26.
  • 3Helen W T. DuPont FEA - 1100: Zero ODP, Low GWP, Non - Flammable Alternative for HCFC - 141b. Zhu G D, Staeger M A, Boyd Steven A. Diels - Alder reac- tions of hexafluoro - 2 - butyne with 2 - heterosubstituted furans : A facile and general synthesis of 1,4 -disubstituted 2,3 - di (trifluoromethyl) benzenes [ J ]. Organic Letters, 2000, (21)2:3345-3348.
  • 4Carpenter W R, Haymaker A, Moore D W. Fluorinated 1, 2,3 - triazolines[J]. J. Org. Chem, 1966,31(3) :789 - 792.
  • 5Brown H C, Gewanter H L. Polymerization of perfluoro - 2 -butyne[J]. J. Org. Chem, 1960, 25:2071.
  • 6Harris J F, Jr. Polymeric perfluoro -2 -butyne: US, 3037010[ P]. 1962 - 05 - 29.
  • 7Huang Y Z, Zhou J Q, Zhu Z M, et al. "tr - Bis (benzene) chromium(0 ) catalyzed cooligomerization of perfluoroprop- ylene and perfluorobut - 2 - yne [ J ]. J. Fluorine Chem, 1986,30(4) :455.
  • 8Huang Y Z, Zhou J Q, Zhu Z M, et al. - Bis (benzene) chromium(0 ) catalyzed cooligomerization of perfluoroprop- ylene and perfluorobut - 2 - yne [ J ]. J. Fluorine Chem, 1986,30(4) :455.
  • 9Frank C E, Blackham A U. Free -radical initiated dimer- izations[J], J. Am. Chem. Soc, 1950,72:3283.
  • 10Henne A L, Trott P. Improved preparation of trifluoroace- tic acid[J]. J. Am. Chem. Soc, 1947,69:1820.

引证文献4

二级引证文献9

有机氟工业
2012年 第1期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部