摘要
二新奇 steroidal saponins (timosaponin 双性人 -- 一, timosaponin BIII-b ) 和已知的 steroidal, saponin (timosaponin BII-b ) 被 timosaponin 的 dilute 酸水解作用准备双性人。他们的结构借助于 1D, 2D NMR 和 TOFMS 被阐明光谱分析。
Two novel steroidal saponins(timosaponin BⅢ-a,timosaponin BⅢ-b) together with a known steroidal saponin(timosaponin BⅡ-b) were prepared by the dilute acid hydrolysis of timosaponin BⅢ.Their structures were elucidated by means of 1D,2D NMR and TOF-MS spectral analysis.
基金
the National Science & Technology Major Project"Key New Drug Creation and Manufacturing Program",China(Nos2009ZX09301-001,2009ZX09102-121,and 2009ZX09501-030)
the State Key Program of National Natural Science Foundation of China(Nos81030065 and 20805054)