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由Mannich反应合成新型Salen配体

Synthesis of New Salen Ligands by Mannich Reaction
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摘要 以乙二胺或乙二胺衍生物为碱,与甲醛、对甲酚通过Mannich反应生成了四种N,N'-双(水杨醛)乙二胺(salen)配体,其中3个为新化合物。其结构经1H NMR,IR,MS和元素分析表征。 Four Salen ligangds（three of them are novel） were synthesized by Mannich condensation of ethanediamine or ethylenediamine derivatives with formaldehyde and p-cresol.The structures were characterized by 1H NMR,IR,MS and elemental analysis.
作者 王暖升 李俊英 李天铎
机构地区 山东轻工业学院山东省轻工助剂重点实验室
出处 《合成化学》 CAS CSCD 北大核心 2012年第2期204-206,213,共4页 Chinese Journal of Synthetic Chemistry
基金 山东省科技攻关计划资助项目(2008GG2CG03001) 山东省高校科技计划资助项目(J09LB03)
关键词 乙二胺 SALEN配体 芳胺 MANNICH反应 合成 ethylenediamine Salen ligand arylamine Mannich reaction synthesis
分类号 O625.63 [理学—有机化学]
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参考文献10

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二级参考文献8

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合成化学
2012年 第2期

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